COSMETIC COMPOSITION COMPRISING A CARBOSILOXANE DENDRIMER-BASED POLYMER AND EXPANDED POLYMER PARTICL

专利摘要:
The present invention relates to a cosmetic composition for the makeup and / or care of keratinous substances, in particular the skin, in the form of a water-in-oil emulsion comprising, in a physiologically acceptable medium, at least one vinyl polymer having at least one unit derived from carbosiloxane dendrimer, and at least 0.5% by weight of expanded polymer particles based on the total weight of the composition.
公开号:FR3015251A1
申请号:FR1363253
申请日:2013-12-20
公开日:2015-06-26
发明作者:Helene Khachikian；Audrey Ricard
申请人:LOreal SA；
IPC主号:

专利说明:

[0001] The present invention relates to the field of care and / or makeup of keratinous substances, and in particular of the skin and mucous membranes. More particularly, the present invention relates to compositions having matt performance, in particular improved resistance to dullness over time.
[0002] By "keratin materials" is meant the skin, the lips, the eyelashes and the eyebrows, and in particular the skin of the face or eyelids, and the eyebrows. Obtaining a matte effect of the skin is highly sought after by users with combination or oily skin, as well as for cosmetic compositions intended to be used in hot and humid climates. Reflections caused by an excess of sebum and / or sweat on the surface of the skin are indeed generally regarded as unsightly. A shiny skin also generally leads to less good hold of the makeup which thus tends to degrade during the day. Cosmetic compositions, such as, for example, foundations, are commonly used to bring a color and an aesthetic effect to the skin, especially to the face. These makeup products generally contain oils, pigments, fillers and possibly additives such as cosmetic or dermatological active ingredients. It is known to those skilled in the art to use fillers to achieve a matt effect. These fillers are most often chosen according to their good absorption properties of sebum and / or their ability to diffuse light. However, their adhesion to the skin is generally low, especially in the presence of sebum. Film-forming polymers can then be used to improve the adhesion of these fillers but also to increase the resistance of the dullness effect during the day. These polymers, in view of their chemical nature, can be carried in the fatty phase or in the aqueous phase. Examples of these polymers include silicone resins, polyacrylates, latices, or those described in US Pat. No. 6,887,859.
[0003] If the presence of this type of polymer actually makes it possible to confer on the cosmetic compositions containing them improved properties of keeping the dullness, it can be unfortunately sometimes detrimental to comfort. Thus, the presence of these polymers can lead to unpleasant sensations and discomfort, either during the application of the composition containing them (difficult spreading, sticky effect, feeling of fat, ...), or during the day (tightness, mask effect ...). More recently, the advantageous properties of vinyl polymers comprising carbosiloxane dendrimer derived units associated with olefin or silica copolymers have been described (see, respectively, EP 1 862 162 and WO 2010/02658). It remains the need to have cosmetic compositions having good cosmetic properties, and in particular providing an effect of dullness effective, immediate, and durable over time. Thus, the present invention aims at providing cosmetic compositions having an immediate dullness and a still improved dullness, which are pleasant and easy to apply, while maintaining a satisfactory application comfort, that is to say do not presenting no feeling of tightness or effect masks throughout the day and / or not inducing a feeling of greasy or sticky during its application. It also aims to provide cosmetic compositions for which the holding of the homogeneity of makeup is also improved. In addition, matte foundations are generally anhydrous foundations. These water-free formulations perform well on the immediate mat and during the day, but their powdery finish and the rather greasy application can limit their potential depending on the market. Thus, the present invention also aims to provide compositions which, in addition to the improved dullness performance mentioned above, provide a more natural makeup and therefore less powdered with a finer deposit in terms of thickness.
[0004] The object of the present invention is to satisfy these needs. Thus, the present invention relates to a cosmetic composition for the makeup and / or care of keratin materials, in particular the skin, in the form of a water-in-oil emulsion comprising, in a physiologically acceptable medium, at least one vinyl polymer having at least one unit derived from carbosiloxane dendrimer, and at least 0.5% by weight of expanded polymer particles relative to the total weight of the composition.
[0005] According to one particular embodiment of the invention, the composition further comprises at least one additional filler, preferably chosen from mattifying or absorbing sebum fillers.
[0006] Unexpectedly, the inventors have observed that the use in a make-up and / or care composition of keratinous substances, in particular of the skin, of a vinyl polymer having at least one unit derived from carbosiloxane dendrimer in combination with at least 0.5% by weight of expanded polymer particles relative to the total weight of the composition provides improved performance in terms of dullness while maintaining satisfactory application comfort. Furthermore, and in addition to the performances of immediate dullness and over time, the nature of the water-in-oil emulsion of a composition according to the invention makes it possible to obtain a more natural makeup, less powdery and especially a thin film. and therefore a feeling less heavy for the user. Without wishing to be bound by any theory, the inventors have observed that when the level of a vinyl polymer having at least one unit derived from carbosiloxane dendrimer is lower than that of the expanded polymer particles, the dullness is less good and when the content of expanded polymer particles is less than 0.5% by weight, the cosmetic properties and matt performance are poorer and / or degraded over time. The subject of the present invention is also the use in a cosmetic composition, in particular of the water-in-oil emulsion, makeup and / or skincare keratin material type, of at least one vinyl polymer having at least one unit derived from carbosiloxane dendrimer in combination with at least 0.5% by weight of expanded polymer particles relative to the total weight of the composition to impart to said composition an improved durability of the dullness. The present invention also relates to a process for the makeup and / or care, especially non-therapeutic, of keratinous substances, in particular the skin, comprising at least the step of applying to said keratinous material at least one layer of a composition according to the invention.
[0007] The composition of the invention may be a skincare and / or makeup base composition or a makeup product for keratin materials. In the case of a makeup base, it is generally applied before a makeup product such as a foundation, to improve the mattness of the makeup result and the holding of this matte over time. According to one embodiment, a composition according to the invention may be contained in a container formed from at least one non-thermoplastic material. According to another embodiment, a composition according to the invention can be contained in a container formed from at least one thermoplastic material. A cosmetic composition of the invention may be in the form of a skincare or make-up base, or a makeup product for keratin materials, in particular the skin, the lips or the eyebrows, in particular a backing. complexion, hot-melt foundation, lipstick, body make-up product, concealer, eyeshadow or eyebrow product. A care composition according to the invention can be in particular a solar composition. It can be fluid or not, and advantageously is fluid. It can also be in the form of soft dough. For the purposes of the present invention, the term "liquid" (or "fluid") is intended to mean a composition capable of flowing under its own weight, at ambient temperature (at 20 ° C.) and at atmospheric pressure (760 mm). Hg), as opposed to solid. 1VIATITE AND HOLDING OF THE VIATITE Maturity and mattness performance can be measured using the protocol described below. The dullness of a region of the skin, for example, the face is measured using a polarimetric camera, which is a polarimetric imaging system in black and white, with which images in parallel polarized light ( P) and crossed (C) are acquired.
[0008] By image analysis resulting from the subtraction of the two images (P-C), the brightness is quantized by measuring the average gray level of the 5% of the brightest pixels corresponding to the areas of brightness. Specifically, the measurements are made on a panel of people, for example, a sample of 16 women, who are kept in the air conditioned waiting room (22 ° C +/- 2 ° C) 15 minutes before the start of the test. They remove their makeup and an image of one of their cheeks is acquired with the polarimetric camera. This image makes it possible to measure the gloss with TO before makeup. Then about 100 mg of cosmetic composition are weighed into a watch glass, and are applied to the bare fingers on the half face on which the TO measurement was performed. After a drying time of 15 minutes, an image of the makeup cheek is acquired with the polarimetric camera. This image measures the brightness just after makeup (Timm). The models then return to the air-conditioned room for 3 hours. Finally, an image of the cheek makeup after 3 hours of waiting is acquired with the polarimetric camera. This image makes it possible to measure the gloss after 3 hours of makeup (T3h). The results are expressed by calculating the difference (Timm - TO) that measures the effect of makeup. A negative value means that the makeup reduces the shine of the skin and is therefore mattifying.
[0009] The difference (T3h - Timm) measuring the behavior of this effect is then calculated. The value obtained must be as low as possible which means that the dullness of the makeup does not change over time. PARTICLES OF EXPANDED POLYMERS A composition according to the invention comprises at least 0.5% by weight of expanded polymer particles relative to the total weight of the composition. The particles are generally in the form of spheres or balls. However, it is possible to use particles in the form of fibers or needles. It is preferable to use particles having an average particle size of 1 to 300 microns (1.1m), for example from 5 to 200 microns, and preferably from 10 to 100 microns, and still more preferably from 15 to 40 microns. .m.
[0010] These particles may be made of different inert materials that do not react chemically with the medium; in particular, these particles do not react with the oils, surfactants, water and the various other constituents of the composition according to the invention.
[0011] The expanded polymer particles are advantageously chosen from particles of thermoplastic materials chosen from polymers or copolymers of acrylonitrile, vinylidene chloride, vinyl chloride and / or acrylic or styrenic monomer, optionally expanded, and microporous microspheres. The acrylic monomer is, for example, a methyl or ethyl acrylate or methacrylate. The styrenic monomer is, for example, methyl styrene or styrene. Thus, according to a particular embodiment, the composition according to the invention comprises hollow particles of expanded acrylonitrile (co-) polymer. These particles are thus derived from at least one polymer, or copolymer, of acrylonitrile. They are made of any polymer or copolymer, acrylonitrile, expanded, non-toxic and non-irritating to the skin. These particles are advantageously spherical. The density of the particles is chosen in the range from 15 kg / m3 to 200 kg / m3 and better still from 30 kg / m3 to 120 kg / m3, and still more preferably from 40 kg / m3 to 80 kg / m3. To obtain this low density, it is advantageous to use particles of polymers or copolymers, expanded, based on acrylonitrile and preferably an acrylic or styrene monomer and / or vinylidene chloride. The internal cavity of the particles in principle contains a gas which may be air, nitrogen or a hydrocarbon such as isobutane or isopentane, preferably isobutane. Preferably, the particles of the invention have a particle size ranging from 1 μm to 80 μm and better still ranging from 10 μm to 50 μm, and more preferably from 20 μm to 40 μm. .m. Advantageously, the expanded polymer particles are deformable hollow particles of an expanded copolymer of vinylidene chloride and acrylonitrile, or vinylidene chloride, acrylonitrile and (meth) acrylate or styrenic monomer. It is possible, for example, to use a polymer containing 0-60% of units derived from vinylidene chloride, 20-90% of units derived from acrylonitrile and 0-50% of units derived from an acrylic or styrenic monomer, the sum of the percentages. (by weight) being equal to 100%. The acrylic monomer is, for example, an acrylate or methyl (meth) acrylate or ethyl acrylate. The styrenic monomer may be styrene or methyl styrene.
[0012] More preferably, the expanded polymer particles used in the present invention are hollow particles of an expanded copolymer of vinylidene chloride and acrylonitrile or vinylidene chloride, acrylonitrile and methyl methacrylate. These particles can be dry or hydrated. The particles of the invention can be obtained, for example, according to the processes of patents and patent applications EP-56219, EP-348372, EP-486080, EP-320473, EP-112807 and US-3615972. The expanded polymer particles that can be used in the invention are, for example, the microspheres of expanded terpolymer of vinylidene chloride, of acrylonitrile and of methyl methacrylate, sold under the trademark Expancel by Akzo Nobel and in particular under the references 551 DE. 12 (particle size D (0.5) of about 12 μm and density of about 40 kg / m 3), 551 DE (particle size D (0.5) of about 15 to 25 μm and density of about 60 kg / m3), 551 DE 50 (particle size D (0.5) of about 40 μm), 461 μm 50 and 642 μm 50 of about 50 μm particle size D (0.5), 551 μm. 80 (particle size D (0.5) from about 50 to 80 μm). It is also possible to use particles of this same expanded terpolymer, having a particle size D (0.5) of approximately 18 μm and a density of approximately 60 to 80 kg / m3 (Expancel EL23) or else of particle size D ( 0.5) of about 34 μm and density of about 20 kg / m3. We can also mention EXPANCEL particles 551 DE 40 d42 (particle size D (0.5) of about 30 to 50 iam and density of about 42 kg / m3), 551 DE 80 d42 (particle size D (0.5) from about 50 to 80 μm and density of about 42 kg / m3), 461 DE 20 d70 (particle size D (0.5) of about 15 to 25 μm and density of about 70 kg / m3), 461 DE 40 d25 (particle size D (0.5) of about 35 to 55 iam and density of about 25 kg / m3), 461 DE 40 d60 (particle size D (0.5) of about 20 to 40 iam and density of about 60 kg / m 3), 461 DET 40 d25 (particle size D (0.5) of about 35 to 55 μm and density of about 25 kg / m 3), 051 DE 40 d 60 (particle size D (0.5) of about 20 to 40 μm and density of about 60 kg / m3), 091 DE 40 d30 (particle size D (0.5) of about 35 to 55 μm and density of about 30 kg / m3), 091 DE 80 d30 (particle size D (0.5) of about 60 to 90 μm and density of about 30 kg / m3). It is also possible to use polymer particles of vinylidene chloride and of acrylonitrile or of vinylidene chloride, of acrylonitrile and of unexpanded methyl methacrylate, such as those sold under the trademark EXPANCEL with the reference 551 DU (particle size D (0). 5) about 10 μm) or 46% (particle size D (0.5) about 15 μm). According to a particularly preferred embodiment, the expanded polymer particles that can be used in the invention are the particles EXPANCEL 551 DE 40 d42 (particle size D (0.5) of approximately 30 to 50 μm and density of approximately 42 kg / According to a particularly preferred embodiment, a composition according to the invention may comprise from 0.5 to 5% by weight of expanded polymer particles relative to the total weight of the composition, in particular from 0.5 to 2, 5%, and more particularly from 0.5 to 1.5% by weight relative to the total weight of the composition As can be seen from the foregoing, a composition according to the invention uses expanded polymer particles with at least at least one vinyl polymer having at least one carbosiloxane dendrimer derivative.
[0013] Advantageously, a composition according to the invention uses a weight ratio "vinyl polymer (s) having at least one carbosiloxane dendrimer derivative / expanded polymer particles" greater than or equal to 6, preferably greater than or equal to 8 , more particularly greater than or equal to 10.
[0014] VINYL POLYMER GRAFTED WITH A CARBOSILOXANE DENDRIMER A vinyl polymer suitable for the preparation of a composition according to the invention comprises at least one unit derived from carbosiloxane dendrimer. The vinyl polymer has a backbone and at least one side chain, which comprises a carbosiloxane dendrimer derived unit having a carbosiloxane dendrimer structure.
[0015] The term "carbosiloxane dendrimer structure" in the context of the present invention represents a molecular structure having branched groups having high molecular weights, said structure having a high regularity in the radial direction from the skeleton bond. Such carbosiloxane dendrimer structures are described in the form of a highly branched siloxane-silylalkylene copolymer in Japanese Patent Application Laid-open Kokai 9-171,154. A vinyl polymer according to the invention may contain derived units. carbosiloxane dendrimers which may be represented by the following general formula (I): R1 _3 Y-Si- (I) wherein: - R1 represents an aryl group of 5 to 10 carbon atoms or an alkyl group of 1 to 10 atoms of carbon ; X 'represents a silylalkyl group which, when i = 1, is represented by the formula (II): (OR3) al R2 Si R1 O Si X' R '3-a' wherein: R1 is as defined herein above in the formula (I), R2 represents an alkylene radical of 2 to 10 carbon atoms, R3 represents an alkyl group of 1 to 10 carbon atoms, X1 + 1 is chosen from: a hydrogen atom, an alkyl group of 1 to 10 carbon atoms, an aryl group of 5 to 10 carbon atoms and a silylalkyl group defined above of formula (II) with i = i + 1, i is an integer of 1 to Which represents the generation of said silylalkyl group, and a 'is an integer from 0 to 3; Y represents a radically polymerizable organic group selected from: organic groups containing a methacrylic group or an acrylic group, said groups organic compounds being represented by the formulas: ## STR1 ## where: R 4 represents a hydrogen atom or an alkyl group of 1 to 10 carbon atoms; and R 5 represents an alkylene group of 1 to 10 carbon atoms, such as a methylene group, an ethylene group, a propylene group, or a butylene group, with methylene and propylene groups being preferred; and. styryl-containing organic groups of the formula: wherein: R 6 represents a hydrogen atom or an alkyl group of 1 to 10 carbon atoms, such as a methyl group, an ethyl group, a propyl group, or a butyl group, the methyl group being preferred; R7 represents an alkyl group of 1 to 10 carbon atoms; R8 represents an alkylene group of 1 to 10 carbon atoms, such as a methylene group, an ethylene group, a propylene group, a butylene group, the ethylene group being preferred; * b is an integer from 0 to 4; and * c is 0 or 1, so that if c is 0, - (R), - represents a bond. In one embodiment, R 'may be an aryl group having 5 to 10 carbon atoms or an alkyl group having 1 to 10 carbon atoms.
[0016] The alkyl group may preferably be methyl, ethyl, propyl, butyl, pentyl, isopropyl, isobutyl, cyclopentyl or cyclohexyl. The aryl group may preferably be represented by a phenyl group and a naphthyl group. The methyl and phenyl groups are more particularly preferred, and the methyl group is most preferred. According to one embodiment, R2 represents an alkylene group having 2 to 10 carbon atoms, especially a linear alkylene group, such as an ethylene, propylene, butylene or hexylene group; or a branched alkylene group, such as a methylmethylene, methylethylene, 1-methylpentylene or 1,4-dimethylbutylene group. Ethylene, methylethylene, hexylene, 1-methylpentylene and 1,4-dimethylbutylene are most preferred.
[0017] According to one embodiment, R3 is chosen from methyl, ethyl, propyl, butyl and isopropyl groups. In formula (II), i indicates the number of generations and thus corresponds to the number of repetitions of the silylalkyl group. For example, when the number of generations is 1, the carbosiloxane dendrimer may be represented by the general formula shown below, wherein Y, R 1, R 2 and R 3 are as defined above, R '2 represents a hydrogen atom or is identical to R1; a 'is identical to a'. Preferably, the total average number of OR3 groups in a molecule is in the range of 0 to 7. I1 (OR3) 2 0 Si R Si I 2 1 O Si RR '3 -al Y Si 3 When the number of generations is equal to 2, the carbosiloxane dendrimer may be represented by the general formula below, wherein Y, R 1, R 2, R 3 and R '2 are the same as defined above; a 'and a2 represent the a' of the indicated generation. Preferably, the total average number of OR3 groups in a molecule is in the range of 0 to 25. Y Si 0 1 2 R (0a3) R 2 RI al Si Si Si Ri Si 0 Pal al 1 a2 2 IR 1 Si If the number of generations is 3, the carbosiloxane dendrimer is represented by the general formula below, wherein Y, R 1, R 2, R 3 and R ' 2 are the same as defined above; al, a2 and a3 represent the a 'of the indicated generation. Preferably, the total average number of OR3 groups in a molecule is in the range of 0 to 79. 1 (OR3) I 2 al 0 Si R Si Ri R1 (Oa3) al-I 2 a2 R1 (ORs) I 2 a3 If a vinyl polymer having at least one unit derived from carbosiloxane dendrimer has a side molecular chain containing a carbosiloxane dendrimer, and may be derived from the polymerization: (A) from 0 to 99.9 parts by weight of a vinyl monomer; and (B) from 100 to 0.1 parts by weight of a radical-polymerizable organic group-containing carbosiloxane dendrimer represented by the general formula (I) as defined above. The vinyl monomer component (A) in the vinyl polymer having at least one carbosiloxane dendrimer-derived unit is a vinyl-type monomer which contains a radical-polymerizable vinyl group. There is no particular limitation with respect to such a monomer. The following are examples of this vinyl type monomer: methyl methacrylate, ethyl methacrylate, n-propyl methacrylate, isopropyl methacrylate, or a lower analogous alkyl methacrylate; glycidyl methacrylate; butyl methacrylate, butyl acrylate, n-butyl methacrylate, isobutyl methacrylate, tert-butyl acrylate, tert-butyl methacrylate, n-hexyl methacrylate, cyclohexyl methacrylate , 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, octyl methacrylate, lauryl methacrylate, stearyl acrylate, stearyl methacrylate, or a higher analogous methacrylate; vinyl acetate, vinyl propionate, or a lower analogous fatty acid vinyl ester; vinyl caproate, vinyl 2-ethylhexoate, vinyl laurate, vinyl stearate, or a higher analogous fatty acid ester; styrene, vinyltoluene, benzyl methacrylate, phenoxyethyl methacrylate, vinylpyrrolidone, or analogous aromatic vinyl monomers; methacrylamide, N-methylolmethacrylamide, N-methoxymethylmethacrylamide, isobutoxymethoxymethacrylamide, N, N-dimethylmethacrylamide, or analogous vinyl monomers which contain amide groups; hydroxyethyl methacrylate, hydroxypropyl alcohol methacrylate, or vinyl-like monomers which contain hydroxyl groups; acrylic acid, methacrylic acid, itaconic acid, crotonic acid, fumaric acid, maleic acid, or analogous vinyl monomers which contain a carboxylic acid group; tetrahydrofurfuryl methacrylate, butoxyethyl methacrylate, ethoxydiethylene glycol methacrylate, polyethylene glycol methacrylate, polypropylene glycol methacrylate, hydroxybutyl vinyl ether, cetyl vinyl ether, 2-ethylhexyl ether and vinyl, or a vinyl-like monomer with ether linkages; methacryloxypropyltrimethoxysilane, polydimethylsiloxane having a methacrylic group on one of its molecular ends, polydimethylsiloxane having a styryl group on one of its molecular ends, or a silicone-like compound having unsaturated groups; butadiene; vinyl chloride; vinylidene chloride; methacrylonitrile; dibutylfumarate; anhydrous maleic acid; anhydrous succinic acid; methacryl ether and glycidyl ether; an organic salt of an amine, an ammonium salt, and an alkali metal salt of methacrylic acid, itaconic acid, crotonic acid, maleic acid, or fumaric acid ; an unsaturated monomer polymerizable with radicals having a sulfonic acid group such as a styrene sulfonic acid group; a quaternary ammonium salt derived from methacrylic acid such as 2-hydroxy-3-methacryloxypropyltrimethylammonium chloride; and an ester of methacrylic acid of an alcohol having a tertiary amine group such as an ester of methacrylic acid and diethylamine. The multifunctional vinyl-type monomers can also be used. The following are examples of such compounds: trimethylolpropane trimethacrylate, pentaerythritol trimethacrylate, ethylene glycol dimethacrylate, tetraethylene glycol dimethacrylate, polyethylene glycol dimethacrylate, 1,4-butanediol dimethacrylate, 1,6-dimethacrylate. hexanediol, neopentyl glycol dimethacrylate, trimethylolpropanetrioxyethyl methacrylate, tris (2-hydroxyethyl) isocyanurate dimethacrylate, tris (2-hydroxyethyl) isocyanurate trimethacrylate, styryl-capped polydimethylsiloxane having divinylbenzene groups on both ends or analogous silicone compounds having unsaturated groups. A carbosiloxane dendrimer, which is the component (B), can be represented by the formula (I) as defined above.
[0018] The following is the preferred examples of group Y of formula (I): an acryloxymethyl group, a 3-acryloxypropyl group, a methacryloxymethyl group, a 3-methacryloxypropyl group, a 4-vinylphenyl group, a 3-vinylphenyl group, a 4- (2-propenyl) phenyl group, 3- (2-propenyl) phenyl group, 2- (4-vinylphenyl) ethyl group, 2- (3-vinylphenyl) ethyl group, vinyl group, allyl group , a methallyl group, and a 5-hexenyl group. A carbosiloxane dendrimer according to the present invention can be represented by the following average structural formulas: ## STR2 ## CH 3 O-Si-C 6 H 12 Si CH 3 CH 3 O-Si-CH, CH 3, 3 3 H 2 C = CH-C-O-C 3 HSi 0 CH 3 O-Si-C 2 H 2 Si CH 3 CH 3 O-Si-CH, CH 3 ## STR5 ## wherein CH, C5H, ## STR1 ## wherein ## STR5 ## wherein CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 Si-C2H, Si CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 ## STR2 ## wherein CH 2 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 1.9 _ 3 (OMe) _ CH I 3 0.5 ## STR5 ## wherein CH 2 CH 3 CH 3 = 2.5 CH 3 H 2 C = CO-C 3 H 18 CH 3 H 2 C = CO-O-CH 3 H 3 O (CH 3); ## STR1 ## Thus, according to one embodiment, , the carbosiloxane dendrimer of the composition according to the present invention is represented by the following formula: (OR 3) I 2 al 0 Si R Si (Oa 3) 1 I 2 a 2 O Si R Si 2 a 3 O Si R Si R - O Si R 12 CH ## STR2 ## where: ## STR2 ## wherein: ## STR2 ## wherein: ## STR2 ## Y, R 1, R 2 and R 3 are as defined in formulas (I) and (II) above; . al, a2 and a3 are as defined in formula (II); and. R'2 is H, an aryl group of 5 to 10 carbon atoms or an alkyl group of 1 to 10 carbon atoms. According to one embodiment, the carbosiloxane dendrimer of the composition according to the present invention is represented by one of the following formulas: ## STR1 ## The vinyl polymer comprising the carbosiloxane dendrimer according to the invention may be manufactured according to the process for the preparation of the vinyl polymer comprising the carbosiloxane dendrimer according to the invention. manufacturing a branched silalkane siloxane described in Japanese Patent Application Hei 9-171,154. For example, it can be produced by subjecting a hydrosilylation reaction to an organosilicon compound which contains a hydrogen atom connected to a silicon atom, represented by the following general formula (IV): wherein R 1 is as defined above in formula (I), and an organosilicon compound which contains an alkenyl group. In the above formula, the organosilicon compound may be represented by 3-methacryloxypropyltri-s (dimethyl siloxy) silane, 3-acryloxypropyltris- (dimethylsiloxy) silane, and 4-vinylphenyltris- (dimethylsiloxy) silane. The organosilicon compound which contains an alkenyl group may be represented by vinyltris- (trimethylsiloxy) silane, vinyltris- (dimethylphenylsiloxy) silane, and 5-hexenyltris (trimethylsiloxy) silane. The hydrosilylation reaction is carried out in the presence of a chloroplatinic acid, a vinylsiloxane and platinum complex, or a transition metal-like catalyst. A vinyl polymer having at least one unit derived from a carbosiloxane dendrimer may be chosen from polymers such that the unit of a derivative of a carbosiloxane dendrimer is a carbosiloxane dendritic structure represented by the formula (III): embedded image is a divalent organic group, "p" is 0 or 1, R 1 is as defined above in formula (IV) and X 'is a silylalkyl group represented by formula (II) as defined above. In a vinyl polymer having at least one unit derived from carbosiloxane dendrimer, the ratio of polymerization between components (A) and (B), in terms of R1 weight ratio between (A) and (B), is in a range of 0/100 to 99.9 / 0.1, or even 0.1 / 99.9 to 99.9 / 0.1, and preferably in a range of 1/99 to 99/1. A ratio between components (A) and (B) of 0/100 means that the compound becomes a homopolymer of component (B).
[0019] A vinyl polymer having at least one unit derived from carbosiloxane dendrimer can be obtained by the copolymerization of the components (A) and (B), or by the polymerization of the single component (B). The polymerization may be free-radical polymerization or ionic polymerization, however radical polymerization is preferred.
[0020] The polymerization can be carried out by causing a reaction between components (A) and (B) in a solution for a period of 3 to 20 hours in the presence of a radical initiator at a temperature of 50 ° C to 150 ° C. A suitable solvent for this purpose is hexane, octane, decane, cyclohexane, or a similar aliphatic hydrocarbon; benzene, toluene, xylene, or a similar aromatic hydrocarbon; diethyl ether, dibutyl ether, tetrahydrofuran, dioxane, or ethers; acetone, methyl ethyl ketone, methyl isobutyl ketone, di-isobutyl ketone, or similar ketones; methyl acetate, ethyl acetate, butyl acetate, isobutyl acetate, or analogous esters; methanol, ethanol, isopropanol, butanol, or similar alcohols; octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, hexamethyldisiloxane, octamethyltrisiloxane, or a similar organosiloxane oligomer. A radical initiator may be any compound known in the art for conventional radical polymerization reactions. Specific examples of such radical initiators are 2,2'-azobis (isobutyronitrile), 2,2'-azobis (2-methylbutyronitrile), 2,2'-azobis (2,4-dimethylvaleronitrile) or compounds azobic analogues; benzoyl peroxide, lauroyl peroxide, tert-butyl peroxybenzoate, tert-butyl peroxy-2-ethylhexanoate, or a similar organic peroxide. These radical initiators can be used alone or in a combination of two or more. The radical initiators may be used in an amount of 0.1 to 5 parts by weight per 100 parts by weight of components (A) and (B). A chain transfer agent can be added. The chain transfer agent may be 2-mercaptoethanol, butyl mercaptan, n-dodecyl mercaptan, 3-mercaptopropyltrimethoxysilane, a polydimethylsiloxane having a mercaptopropyl group or a mercapto-like compound; methylene chloride, chloroform, carbon tetrachloride, butyl bromide, 3-chloropropyltrimethoxysilane, or a similar halogenated compound. In the manufacture of the vinyl polymer, after the polymerization, the unreacted residual vinyl monomer can be removed under vacuum heating conditions. To facilitate the preparation of raw material for cosmetics, the number average molecular weight of the vinyl polymer which contains a carbosiloxane dendrimer may be selected in the range of from 3,000 to 2,000,000, preferably from 5,000 to 800,000. It can be a liquid, an eraser, a paste, a solid, a powder, or any other form. Preferred forms are solutions consisting of dilution in solvents, a dispersion, or a powder. The vinyl polymer may be a dispersion of a vinyl polymer having a carbosiloxane dendrimer structure in its side molecular chain, in a liquid such as a silicone oil, an organic oil, an alcohol, or water. The silicone oil may be a dimethylpolysiloxane having both trimethylsiloxy-capped molecular ends, a copolymer of methylphenylsiloxane and dimethylsiloxane having both trimethylsiloxy-capped molecular ends, a methyl-3,3,3-trifluoropropylsiloxane copolymer, and dimethylsiloxane having both trimethylsiloxy-terminated molecular ends, or analogous non-reactive linear silicone oils, as well as hexamethylcyclotrisiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, or a similar cyclic compound. In addition to the nonreactive silicone oils, modified polysiloxanes having functional groups such as silanol groups, amino groups, and polyether groups on the ends or within the side molecular chains may be used. The organic oils may be isododecane, paraffin oil, isoparaffin, hexyl laurate, isopropyl myristate, myristyl myristate, cetyl myristate, 2-octyldodecyl myristate; isopropyl palmitate, 2-ethylhexyl palmitate, butyl stearate, decyl oleate, 2-octyldodecyl oleate, myristyl lactate, cetyl lactate, lanolin acetate, stearic alcohol, cetostearyl alcohol, oleic alcohol, avocado oil, almond oil, olive oil, cocoa oil, jojoba oil, gum, sunflower oil, soybean oil, camellia oil, squalane, castor oil, cottonseed oil, coconut oil, yellow oil egg, polypropylene glycol monooleate, neopentyl glycol 2-ethylhexanoate, or a similar glycol ester oil; triglyceryl isostearate, triglyceride of a coconut oil fatty acid, or a similar polyhydric alcohol ester oil; polyoxyethylene lauryl ether, polyoxypropylene cetyl ether, or a similar polyoxyalkylene ether. The alcohol may be of any type suitable for use in conjunction with a raw material of cosmetics. For example, it may be methanol, ethanol, butanol, isopropanol or lower alcohols. A solution or dispersion of the alcohol should have a viscosity in the range of 10 to 109 mPa at 25 ° C. To improve the feel properties of use in a cosmetic product, the viscosity should be in the range of 100 to 5 x 108 mPa.s.
[0021] The solutions and dispersions can easily be prepared by mixing a vinyl polymer having at least one carbosiloxane dendrimer derived unit, a silicone oil, an organic oil, an alcohol, or water. The liquids may be present in the polymerization step. In this case, the unreacted residual vinyl monomer should be completely removed by heat treatment of the solution or dispersion under atmospheric or reduced pressure. In the case of a dispersion, the dispersity of the vinyl polymer can be improved by adding a surfactant. Such an agent may be hexylbenzenesulfonic acid, octylbenzenesulfonic acid, decylbenzenesulfonic acid, dodecylbenzenesulfonic acid, cetylbenzenesulfonic acid, myristylbenzenesulfonic acid, or anionic surfactants of the sodium salts. of these acids; octyltrimethylammonium hydroxide, dodecyltrimethylammonium hydroxide, hexadecyltrimethylammonium hydroxide, octyl dimethylbenzylammonium hydroxide, decyldimethylbenzylammonium hydroxide, dioctadecyldimethylammonium hydroxide, beef tallow hydroxide trimethylammonium, coconut trimethylammonium oil hydroxide, or a similar cationic surfactant; a polyoxyalkylene alkyl ether, a polyoxyalkylenealkylphenol, a polyoxyalkylene alkyl ester, polyoxyalkylene sorbitol ester, polyethylene glycol, polypropylene glycol, a diethylene glycol trimethylnonanol ethylene oxide additive, and surfactants; Nonionic, polyester-type actives, as well as mixtures.
[0022] In the dispersion, a mean diameter of the vinyl polymer particles may be in the range of 0.001 to 100 microns, preferably 0.01 to 50 microns. Indeed, beyond the recommended range, a cosmetic product mixed with the emulsion will not have a sufficiently good sensation on the skin or touch, nor sufficient spreading properties nor a pleasant sensation.
[0023] A vinyl polymer contained in the dispersion or solution may have a concentration in a range of between 0.1% and 95% by weight, preferably between 5% and 85% by weight. However, for ease of handling and mixing, the range should preferably be between 10% and 75% by weight. A vinyl polymer that is suitable for the invention may also be one of the polymers described in the examples of application EP 0 963 751. According to one preferred embodiment, a vinyl polymer grafted with a carbosiloxane dendrimer may be derived from the polymerization: ) from 0 to 99.9 parts by weight of one or more acrylate or methacrylate monomer (s); and (B) from 100 to 0.1 parts by weight of an acrylate or methacrylate monomer of a tri [tri (trimethylsiloxy) silylethyl dimethylsiloxy] silylpropyl carbosiloxane dendrimer. The monomers (A1) and (B1) correspond to particular monomers (A) and (B), respectively.
[0024] According to one embodiment, a vinyl polymer having at least one unit derived from carbosiloxane dendrimer may comprise a unit derived from tri [tri (trimethylsiloxy) silylethyl dimethylsiloxy] silylpropyl carbosiloxane dendrimer having one of the following formulas: CH 3 CH 3 CH 3 H 2 C = In a preferred embodiment, a vinyl polymer having at least one of at least one of at least one of at least one vinyl polymer and at least one of which may be used. a carbosiloxane dendrimer derived unit used in the invention comprises at least one butyl acrylate monomer. According to one embodiment, a vinyl polymer may further comprise at least one fluorinated organic group.
[0025] Particularly preferred are structures in which the vinyl polymerized units constitute the backbone and carbosiloxane dendritic structures as well as fluorinated organic groups are attached to side chains. The fluorinated organic groups may be obtained by substituting with fluorine atoms all or part of the hydrogen atoms of methyl, ethyl, propyl, isopropyl, butyl, isobutyl, tert-butyl, pentyl, neopentyl, hexyl, cyclohexyl and heptyl groups, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, hexadecyl, octadecyl, and other alkyl groups of 1 to 20 carbon atoms, as well as alkyloxyalkylene groups of 6 to 22 carbon atoms. The groups represented by the formula - (CH 2) '- (CF 2) 5, -R "are suggested by way of example of fluoroalkyl groups, obtained by substituting fluorine atoms for hydrogen atoms of alkyl groups. formula, the index "x" and 0, 1, 2 or 3 and "y" and an integer of 1 to 20. Rn is an atom or a group selected from a hydrogen atom, a fluorine atom, -CH (CF 3) 2- or CF (CF 3) 2 Such fluorine-substituted alkyl groups are exemplified by linear or branched polyfluoroalkyl or perfluoroalkyl groups represented by the formulas presented below: - CF 3, -C 2 F 5, -nC 3 F 7, - CF (CF3) 2, -NC4F9, CF2CF (CF3) 2, -NC5Fi, -NC6F13, -NC8F17, CH2CF3, - (CH (CF3) 2, CH2CH (CF3) 2-CH2 (CF2) 2F, -CH2 (CF2 ) 3F, -CH2 (CF2) 4F, CH2 (CF2) 6F, CH2 (CF2) 8F, -CH2CH2CF3, -CH2CH2 (CF2) 2F, -CH2CH2 (CF2) 3F, -CH2CH2 (CF2) 4F, -CH2CH2 (CF2 ) 6F, -CH2CH2 (CF2) 8F, -CH2CH2 (CF2) 10F, -CH2CH2 (CF2) 12F, CH2CH2 (CF2) 14F, -CH2CH2 (CF2) 16F, -CH2CH2CH2CF3, -CH2CH2CH2 (CF2) 2F, -CH2CH2CH2 (CF2) 2H, -CH2 (CF2) 4H and -CH2CH2 (CF2) 3H.
[0026] The groups represented by -CH2CH2- (CF2) .- - CFR1440CF2CF (CF3)] nC3F7 are suggested as fluoroalkyloxyfluoroalkylene groups obtained by substituting fluorine atoms for hydrogen atoms of alkoxyoxyalkylene groups. In the formula, the index "m" is 0 or 1, "n" is 0, 1, 2, 3, 4, or 5, and R14 is a fluorine atom or CF3. Such fluoroalkyloxyfluoroalkylene groups are exemplified by perfluoroalkyloxyfluoroalkylene groups represented by the formulas set forth below: -CH2CH2CF (CF3) 40CF2CF (CF3) L-OC3F7, CH2CH2CF2CF240CF2CF (CF3) L-OC3F7. The number average molecular weight of the vinyl polymer used in the present invention may range from 3,000 to 2,000,000, and more preferably from 5,000 to 800,000. This type of fluorinated vinyl polymer may be obtained by adding: a vinyl monomer (M2) without a fluorinated organic group, on a vinyl monomer (M1) containing fluorinated organic groups, and a carbosiloxane dendrimer (B) as defined above of general formula (I) as defined herein. above, subjecting them to copolymerization. Thus, according to one embodiment, a composition of the invention may comprise a vinyl polymer having at least one unit derived from carbosiloxane dendrimer and resulting from the copolymerization of a vinyl monomer (M1) as defined above, optionally a vinyl monomer (M2) as defined above, and a carbosiloxane dendrimer (B) as defined above, said vinyl polymer having a copolymerization ratio between the monomer (M1) and the monomer ( M2) from 0.1 to 100: 99.9 to 0% by weight, and a copolymerization ratio between the sum of the monomers (M1) and (M2) and the monomer (B) of from 0.1 to 99.9: 99.9 to 0.1% by weight. The vinyl monomers (M1) containing fluorinated organic groups in the molecule are preferably monomers represented by the general formula: (cH2) = cecooRf.
[0027] In this formula, R15 is a hydrogen atom or a methyl group, Rf is a fluorinated organic group exemplified by the fluoroalkyl and fluoroalkyloxyfluoroalkylene groups described above. The compounds represented by the formulas presented below are suggested as specific examples of the component (M1).
[0028] In the formulas present below, "z" is an integer of 1 to 4. CH 2 = CCH 3 COO-CF 3, CH 2 = CCH 3 C00-C 2 F 5, CH 2 = CCH 3 C 00-nC 3 F 7, CH 2 = CCH 3 CO-CF (CF 3) 2, CH 2 = CCH 3 CO -NC4F9, CH2 = CCH3C00-CF (CF3) 2, CH2 = CCH3COO-nCSfi1, CH2 = CCH3COO-nC6F13, CH2 = CCH3C00-nC8F17, CH2 = CCH3COO-CH2CF3, CH2 = CCH3C00-CH (CF3) 2, CH2 = CCH3C00; -CH2CH (CF3) 2, CH2 = CCH3C00-CH2 (CF2) 2F, CH2 = CCH3C00-CH2 (CF2) 2F, CH2 = CCH3C00-CH2 (CF2) 4F, CH2 = CCH3C00-CH2 (CF2) 6F, CH2 = CCH3COO -CH2 (CF2) 8F, CH2 = CCH3COO-CH2CH2CF3, CH2 = CCH3C00-CH2CH2 (CF2) 2F, CH2 = CCH3COO-CH2CH2 (CF2) 3F, CH2 = CCH3COO-CH2CH2 (CF2) 4F, CH2 = CCH3COO-CH2CH2 (CF2 ) 6F, CH2 = CCH3COO-CH2CH2 (CF2) 8F, CH2 = CCH3C00-CH2CH2 (CF2) 10F, CH2 = CCH3C00-CH2CH2 (CF2) 12F, CH2 = CCH3C00-CH2CH2 (CF2) 14F, CH2 = CCH3C00-CH2-CH2 - (CF2) 16F, CH2 = CCH3COO-CH2CH2CH2CF3, CH2 = CCH3C00-CH2CH2CH2 (CF2) 2F, CH2 = CCH3C00-CH2CH2CH2 (CF2) 2H, CH2 = CCH3COO-CH2 (CF2) 4H, CH2 = CCH3COO- (CF2) 3H , CH2 = CCH3C00-CH2CH2CF (CF3) - [OCF2-CF (CF3) p-OC3F7, CH2 = CCH3C00-CH2CH2CF2CF240CF2-CF (CF3) p-OC3F7, CH2 = CHCOO-CF3, CH2 = CHCOO-C2F5, CH2 = CHCOO -nC3F7, CH2 = CHCOO-CF (CF3) 2, CH2 = CHCOO-nC4F9, CH2 = CHCOO-CF2CF (CF3) 2, CH2 = CHCOO-nC5Fi, CH2 = CHCOO-nC6F13, CH2 = CHCOO-nC8F17, CH2 = CHCOO-CH2CF3, CH2 = CHCOO-CH (CF3) 2, CH2 = CHCOO-CH2CH (CF3) 2, CH2 = CHCOO-CH2 (CF2) 2F, CH2 = CHCOO-CH2 (CF2) 3F, CH2 = CHCOO-CH2 (CF2) 4F, CH2 = CHCOO-CH2 (CF2) 6F, CH2 = CHCOO-CH2 (CF2) 8F, CH2 = CHCOO-CH2CH2CF3, CH2 = CHCOO-CH2CH2 (CF2) 2F, CH2 = CHCOO-CH2CH2 (CF2) 3F, CH2 = CHCOO-CH2CH2 (CF2) 4F, CH2 = CHCOO-CH2CH2 (CF2) 6F, CH2 = CHCOO-CH2CH2 (CF2) 8F, CH2 = HCOO-CH2CH2 (CF2) 10F, CH2-CHCOO-CH2CH2- (CF2) 12F, CH2 = CHCOO-CH2CH2 (CF2) 14F, CH2 = CHCOO-CH2CH2 (CF2) 16F, CH2 = CHCOO-CH2CH2CH2CF3, CH2 = CHCOO-CH2CH2CH2 (CF2) 2F, CH2 = CHCOO-CH2CH2CH2 (CF) 2H, CH2 = CHCOO-CH2 (CF2) 4H, CH2 = CHCOO-CH2CH2 (CF2) 31-1, CH2 = CHCOO-CH2CH2CF (CF3) -, [OCF2-CF (CF3)] z-OC3F7, CH2 = CHCOO-CH2CH2CF2CF2 (CF3) 40CF2-CF (CF3)] 2-C3F7. Of these, the vinyl polymers represented by the formulas presented below are preferred: CH2 = CHCOO-CH2CH2 (CF2) 6F, CH2 = CHCOO-CH2CH2 (CF2) 8F, CH2 = CCH3C00-CH2CH2 (CF2) 6F, CH2 = CCH3C00-CH2CH2 (CF2) 8F, CH2 = CHCOO-CH2CF3, CH2 = CCH3C00-CH2CF3. The vinyl polymers represented by the formulas presented below are particularly preferred: CH2 = CHCOO-CH2CF3, CH2 = CCHCOO-CH2CF3. The vinyl monomers (M2) which do not contain fluorinated organic groups in the molecule may be any monomers having radical-polymerizable vinyl groups which are exemplified, for example, by methyl acrylate, methyl methacrylate or acrylate. ethyl, ethyl methacrylate, n-propyl acrylate, n-propyl methacrylate, isopropyl acrylate, isopropyl methacrylate, and other lower alkyl acrylates or methacrylates; glycidyl acrylate, glycidyl methacrylate; n-butyl acrylate, n-butyl methacrylate, isobutyl acrylate, isobutyl methacrylate, tert-butyl acrylate, tert-butyl methacrylate, n-hexyl acrylate , n-hexyl methacrylate, n-hexyl acrylate, n-hexyl methacrylate, cyclohexyl acrylate, cyclohexyl methacrylate, 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, octyl acrylate, octyl methacrylate, lauryl acrylate, lauryl methacrylate, stearyl acrylate, stearyl methacrylate, and other higher acrylates and methacrylates; vinyl acetate, vinyl propionate, and other lower fatty acid vinyl esters; vinyl butyrate, vinyl caproate, vinyl 2-ethylhexanoate, vinyl laurate, vinyl stearate, and other higher fatty acid esters; styrene, vinyltoluene, benzyl acrylate, benzyl methacrylate, phenoxyethyl acrylate, phenoxyethyl methacrylate, vinylpyrrolidone, and other vinyl aromatic monomers; dimethylaminoethyl acrylate, dimethylaminoethyl methacrylate, diethylaminoethyl acrylate, diethylaminoethyl methacrylate, and other vinyl amino monomers, acrylamide, methacrylamide, N-methylolacrylamide, N-methylolmethacrylamide, N-methoxymethylacrylamide N-methoxymethacrylamide, isobutoxymethoxyacrylamide, isobutoxymethoxymethacrylamide, N, N-dimethylacrylamide, N, N-dimethylmethacrylamide, and other vinyl amide monomers; hydroxyethyl acrylate, hydroxyethyl methacrylate, hydroxypropyl acrylic acid alcohol, methacrylic acid hydroxypropyl alcohol and other hydroxy vinyl monomers; acrylic acid, methacrylic acid, itaconic acid, crotonic acid, fumaric acid, maleic acid, and other carboxylic acid vinyl monomers; tetrahydrofurfuryl acrylate, tetrahydrofurfuryl methacrylate, butoxyethyl acrylate, butoxyethyl methacrylate, ethoxydiethylene glycol acrylate, ethoxydiethyleneglycol methacrylate, polyethyleneglycol acrylate, polyethyleneglycol methacrylate, polypropyleneglycol monoacrylate polypropylene glycol monomethacrylate, hydroxybutylvinylether, cetylvinylether, 2-ethylhexylvinylether and other ether-linked vinyl monomers; Acryloxypropyltrimethoxy silane, methacryloxypropyltrimethoxysilane, polydimethylsiloxanes containing acrylic or methacryl groups at one end, polydimethylsiloxanes containing alkenylaryl groups at one end and other silicone compounds with unsaturated groups; butadiene; vinyl chloride; vinylidene chloride, acrylonitrile, methacrylonitrile; dibutyl fumarate; maleic anhydride; dodecylsuccinic anhydride; acrylglycidyl ether, methacrylglycidyl ether, 3,4-epoxycyclohexylmethyl acrylate, 3,4-epoxycyclohexylmethyl methacrylate, alkali metal salts, ammonium salts and organic amine salts of acrylic acid, methacrylic acid, itaconic acid, crotonic acid, fumaric acid, maleic acid and other radical-polymerizable unsaturated carboxylic acids, radical-polymerizable unsaturated monomers containing sulfonic acid groups such as styrenesulfonic acid as well as their alkali metal salts, their ammonium salts and their organic amine salts; quaternary ammonium salts derived from acrylic acid or methacrylic acid such as 2-hydroxy-3-methacryloxypropyltrimethylammonium chloride, methacrylic acid esters of a tertiary amine alcohol, such as diethylamine ester, methacrylic acid and their quaternary ammonium salts. In addition, it is also possible to use, as vinyl monomers (M2), the polyfunctional vinyl monomers which are exemplified for example by trimethylolpropane triacrylate, trimethylolpropane trimethacrylate, pentaerythritol triacrylate, pentaerythritol trimethacrylate and diacrylate. ethylene glycol, ethylene glycol dimethacrylate, tetraethylene glycol diacrylate, tetraethylene glycol dimethacrylate, polyethylene glycol diacrylate, polyethylene glycol dimethacrylate, 1,4-butanediol diacrylate, 1,4-butanediol dimethacrylate, diacrylate 1,6-hexanediol, 1,6-hexanediol dimethacrylate, neopentyl glycol diacrylate, neopentyl glycol dimethacrylate, trimethylolpropanetrioxyethyl acrylate, trimethylolpropanetrioxyethyl methacrylate, tris (2-hydroxyethyl) isocyanurate diacrylate, dimethacrylate tris (2-hydroxyethyl) isocyanurate, tris (2-hydroxyethyl) isocyanurate triacrylate, tris (2-hydroxyethyl) isocyanurate trimethacrylate, polydimethylsiloxane whose both ends of the molecular chain are blocked by alkenylaryl groups, and other silicone compounds with unsaturated groups. With respect to the above-mentioned ratio in which (M1) and (M2) are copolymerized, the weight ratio between (M1) and (M2) is preferably in the range 1:99 to 100: 0. Y may be chosen, for example, from organic groups containing acrylic or methacrylic groups, organic groups containing alkenylaryl groups, or alkenyl groups of 2 to 10 carbon atoms. The organic groups with acrylic or methacrylic groups and the alkenylaryl groups are as defined above. Among the compounds (B), there may be mentioned, for example, the following compounds: ## STR3 ## where: ## STR2 ## The carbosiloxane dendrimers (B) can be prepared using the preparation method for the branched siloxane / silakylene copolymers described in EP 1 055 674. For example, they can be prepared by subjecting organic silicone compounds to alkenyl and silicone compounds comprising silicon-bonded hydrogen atoms, represented by the formula (IV) as defined above, to a hydrosilylation reaction. The copolymerization ratio (by weight) between the monomer (B) and the monomers (M1) and (M2) is preferably in the range of 1:99 to 99: 1, and even more preferably in the range of : 95 to 95: 5.
[0029] Amino groups may be introduced into the side chains of the vinyl polymer using, included in the component (M2), vinyl monomers containing amino groups, such as dimethylaminoethyl acrylate, dimethylaminoethyl methacrylate, diethylaminoethyl acrylate and diethylaminoethyl methacrylate, followed by modification with potassium acetate monochloride, ammonium acetate monochloride, monochloroacetic acid aminomethylpropanol salt, monobromoacetic acid triethanolamine salt, sodium monochloropropionate, and other alkali metal salts of halogenated fatty acids; otherwise, carboxylic acid groups can be introduced into the side chains of the vinyl polymer by using, included in the component (M2), vinyl monomers containing carboxylic acids, such as acrylic acid, methacrylic acid, itaconic acid. , crotonic acid, fumaric acid and maleic acid, and the like, then neutralizing the product with triethylamine, diethylamine, triethanolamine, and other amines. A fluorinated vinyl polymer may be one of the polymers described in the examples of application WO 03/045337.
[0030] According to a preferred embodiment, a grafted vinyl polymer in the sense of the present invention may be carried in an oil or a mixture of oil (s), preferably volatile (s) in particular, chosen (s) from the oils of silicones and hydrocarbon oils and mixtures thereof. According to a particular embodiment, a silicone oil that is suitable for the invention may be cyclopentasiloxane. According to another particular embodiment, a hydrocarbon oil suitable for the invention may be isododecane. The vinyl polymers grafted with at least one unit derived from carbosiloxane dendrimer which may be particularly suitable for the present invention are the polymers sold under the names TIB 4-100, TIB 4-101, TIB 4-120, TIB 4- 130, TIB 4- 200, FA 4002 ID (TIB 4-202), TIB 4-220, FA 4001 CM (TIB 4-230) by Dow Corning. According to one embodiment, the composition according to the present invention comprises the vinyl polymer having at least one unit derived from carbosiloxane dendrimer in an active material content ranging from 3% to 15% by weight relative to the total weight of the composition, in particular ranging from 4% to 10% by weight, and more particularly ranging from 5% to 8% by weight of vinyl polymer active material having at least one unit derived from carbosiloxane dendrimer.
[0031] ADDITIONAL LOADS A composition in accordance with the invention may also advantageously comprise at least one additional filler, of organic or mineral nature, making it possible, in particular, to confer on it additional properties of coverage, and dullness and / or improved stability with regard to the exudation and non-migration properties after application.
[0032] In particular, the composition of the invention comprises at least one additional organic filler, and possibly also at least one inorganic filler. Preferably, the organic filler / inorganic filler weight ratio is greater than 1. "Filler" is understood to mean colorless or white, solid particles of all shapes, which are in an insoluble form and dispersed in the medium of the composition . Of mineral or organic nature, they make it possible to impart body or stiffness to the composition and / or softness, dullness and uniformity to make-up. The fillers used in the compositions according to the present invention may be of lamellar, globular, spherical, fiber or any other intermediate form between these defined forms. Preferably, the composition of the invention comprises at least spherical fillers. The fillers according to the invention may or may not be superficially coated, and in particular they may be surface-treated with silicones, amino acids, fluorinated derivatives or any other substance which promotes dispersion and compatibility of the filler in the process. composition. Organic fillers include colorless or white, organic, lamellar or non-lamellar particles. Polyamide powders (Nylon® or Orgasol® from Arkema), acrylic polymer powders, in particular polymethyl methacrylate, polyethyl methacrylate / ethylene glycol dimethacrylate, and allyl polymethacrylate powders may be mentioned in particular. ethylene glycol dimethacrylate / lauryl methacrylate copolymer, cellulose, poly-13-alanine and polyethylene powders, tetrafluoroethylene (Teflon®) polymer powders, lauroyl-lysine, starch, polymeric hollow microspheres of acrylic acid copolymers (Polytrap® from Dow Corning) and silicone resin microspheres (Toshiba Tospearls®, for example), elastomeric polyorganosiloxane particles, especially obtained by polymerization of d organopolysiloxane having at least two hydrogen atoms each bonded to a silicon atom and an organopolysiloxane comprising at least two groups ethylenically unsaturated (especially two vinyl groups) in the presence of platinum catalyst, or metal soaps derived from organic carboxylic acids having from 8 to 22 carbon atoms, preferably from 12 to 18 carbon atoms, for example the stearate of zinc, magnesium or lithium, zinc laurate, magnesium myristate. By mineral fillers, it is necessary to include colorless or white, mineral, lamellar or non-lamellar particles. The mineral fillers may be of any form, such as in particular patatoïde, lamellar, platelet, spherical or oblong. They can be of any crystallographic form (for example sheetlet, cubic, hexagonal, orthorhombic, etc.). Mention may in particular be made of talc, mica, silica, kaolin, boron nitride, precipitated calcium carbonate, magnesium carbonate and hydrocyanate, hydroxyapatite, and hollow silica microspheres (Silica Beads). ® from Maprecos), or microcapsules of glass or ceramic, clay, quartz, natural diamond powder or their mixture. Matifying or absorbent sebum fillers According to a preferred embodiment, the skilled person is interested in the context of the invention to additional mattifying charges. Thus, according to one particular embodiment, the composition of the invention comprises, as additional filler, at least one mattifying or absorbent filler of sebum (filler having a capacity to absorb and / or adsorb an oil or a liquid fatty substance such as for example sebum (of the skin)). This oil-absorbing filler can also advantageously have a BET specific surface area greater than or equal to 300 m 2 / g, preferably greater than 500 m 2 / g, and preferably greater than 600 m 2 / g, and especially less than 1500 m 2 / g .
[0033] The "BET surface area" is determined according to the BET method (BRUNAUER - EMMET - TELLER) described in "The Journal of the American Chemical Society", vol. 60, page 309, February 1938 and corresponding to the international standard ISO 5794/1 (Appendix D). The BET surface area corresponds to the total specific surface area (therefore micropores included) of the powder.
[0034] The mattifying filler may thus have an oil uptake greater than or equal to 1 ml / g, in particular ranging from 1.5 ml / g to 20 ml / g, or even ranging from 1.5 ml / g to 15 ml / g. This oil intake, which corresponds to the amount of oil absorbed and / or adsorbed by the feedstock, can be characterized by measuring the Wet Point according to the method described below. Measurement method for setting oil of a charge: The oil intake of a powder is measured according to the method for determining the setting of powder oil described in standard NF T 30-022. It corresponds to the quantity of oil adsorbed on the available surface of the load by measuring the Wet Point. A quantity m (in grams) of powder of between about 0.5 g and 5 g (the amount depends on the density of the powder) is placed on a glass plate and then isononyl isononanoate is added dropwise. . After the addition of 4 to 5 drops of isononyl isononanoate, the isononyl isononanoate is incorporated in the feed with the aid of a spatula and isononyl isononanoate is added to the formation of conglomerates of isononyl isononanoate and powder. From this moment, the isononyl isononanoate is added one drop at a time and then the mixture is triturated with the spatula. The addition of the isononyl isononanoate is discontinued when a firm and smooth paste is obtained. This paste should be spread on the glass plate without cracks or lumps. The volume Vs (expressed in ml) of isononyl isononanoate used is then noted.
[0035] The oil intake corresponds to the ratio Vs / m. The mattifying filler according to the invention may be of organic or inorganic nature. It may be more particularly chosen from silicas, silylate silicas, polyamide powders (in particular nylon-6 or nylon-12), acrylic polymer powders, in particular polymethyl methacrylate, poly methyl methacrylate / dimethacrylate, and the like. ethylene glycol, allyl polymethacrylate / ethylene glycol dimethacrylate, ethylene glycol dimethacrylate / lauryl methacrylate copolymer; pearlites; carbonate magnesium, and mixtures thereof.
[0036] According to a particularly preferred embodiment, the composition of the invention comprises at least one matting organic filler, in particular chosen from polyamide powders such as Nylon® or Orgasol® from Arkema.
[0037] In this respect, mention may be made of nylon 6, nylon 6-6, nylon 12 or nylon 6-12 particles such as those marketed by ATOFINA under the generic name "Orgasol". Preferably, the organic porous particles of the nylon type are chosen from nylon 12 particles. A composition of the invention may thus comprise from 2 to 15% by weight of organic fillers, preferably mattifying, with respect to the total weight of the composition. in particular from 3 to 10% and even more particularly from 5 to 8% by weight, relative to the total weight of the composition.
[0038] According to an advantageous embodiment, the composition comprises at least one mattifying organic filler and in addition at least one inorganic filler, preferably a silica. A composition according to the invention thus advantageously comprises at least one organic filler, in particular chosen from polyamide powders, optionally also associated with a mineral filler such as silica. The presence of silica in a composition according to the invention is particularly interesting in that it further contributes to the improvement of the cosmetic properties of said composition. A silica that is suitable for the invention is a hydrophilic or hydrophobic silica chosen from precipitated silicas, pyrogenic silicas, and mixtures thereof. A silica suitable for the invention may be spherical or non-spherical, porous or non-porous. Preferably, a silica that is suitable for the invention is spherical and porous.
[0039] As silica powder having a matting effect, mention may be made of: the porous silica microspheres sold under the name SILICA BEADS SB-700 by the company MYOSHI; "SUNSPHERE® H51", "SUNSPHERE® H33" by the company ASAHI GLASS; and the amorphous silica microspheres coated with polydimethylsiloxane sold under the name SA Sunsphere® H 33, SA Sunsphere H53 by ASAHI GLASS.
[0040] As silica powder having mattifying properties, mention may be made of: porous silica microspheres, in particular those sold under the name Sunsphere® H53, Sunsphere® H33 by the company Asahi Glass; MSS-500-3H by the company KOBO; the amorphous silica microspheres coated with polydimethylsiloxane, in particular those sold under the name SA Sunsphere® H 33, the silylate powders, in particular those sold under the name Dow Corning VM-2270 Aerogel Fine Particles by the company Dow Corning and hollow particles of amorphous silicas, especially those sold under the name Silica Shells by Kobo. A composition of the invention may comprise from 0.5 to 15% by weight of mineral filler preferably mattifying, such as silica, relative to the total weight of the composition, in particular from 2 to 10% and even more particularly from 3 to 7% by weight relative to the total weight of the composition. The total charge content in the composition, including the expanded polymer particles and the additional charges mentioned above, can vary to a large extent depending on the nature of the charge and also depending on the desired product and / or the desired effects, quantity is to be adapted by the person skilled in the art. Thus, the total filler content (s), especially when the composition comprises additional charges distinct from the expanded polymer particles, will be from 3 to 20% by weight relative to the total weight of the composition, preferably from 8 to 20% by weight relative to the total weight of the composition. 15% by weight, or even 10 to 15% by weight relative to the total weight of said composition. Thus, according to a particularly advantageous embodiment, a composition according to the invention uses a weight ratio "vinyl polymer (s) having at least one carbosiloxane dendrimer derivative / total charges, especially when the composition comprises fillers. separate additional particles of expanded polymers, less than 1, preferably less than 0.6, and better still less than 0.5. PHYSIOLOGICALLY ACCEPTABLE MEDIUM In addition to the compounds indicated above, a composition according to the invention comprises a physiologically acceptable medium. By "physiologically acceptable medium" is meant a medium which is particularly suitable for the application of a composition of the invention to keratin materials and in particular the skin, the lips or the eyebrows.
[0041] The physiologically acceptable medium is generally adapted to the nature of the medium to which the composition is to be applied, as well as to the appearance under which the composition is to be packaged. As indicated above, a composition according to the invention is an inverse emulsion (W / O).
[0042] Aqueous Phase The composition according to the invention comprises an aqueous phase. The aqueous phase comprises water. A water suitable for the invention may be a floral water such as cornflower water and / or mineral water such as VITTEL water, LUCAS water or LA ROCHE POSAY water and / or a thermal water. The aqueous phase may also comprise water-miscible organic solvents (at ambient temperature -25 ° C.), for example monoalcohols having from 2 to 6 carbon atoms, such as ethanol or isopropanol; the polyols having in particular 2 to 20 carbon atoms, preferably having 2 to 10 carbon atoms, and preferably having 2 to 6 carbon atoms, such as glycerol, propylene glycol, butylene glycol, pentylene glycol, hexylene glycol, dipropylene glycol, diethylene glycol; glycol ethers (having in particular from 3 to 16 carbon atoms) such as the (C 1 -C 4) alkyl ether of mono-, di- or tripropylene glycol, the (C 1 -C 4) alkyl ethers of mono-, di- or triethylene glycol , and their mixtures. The aqueous phase may further comprise stabilizing agents, for example sodium chloride, magnesium dichloride and magnesium sulfate.
[0043] The aqueous phase may also comprise any water-soluble or water-dispersible compound compatible with an aqueous phase such as gelling agents, film-forming polymers, thickeners, surfactants and mixtures thereof.
[0044] In particular, a composition of the invention may comprise an aqueous phase in a content ranging from 1% to 80% by weight, especially from 5% to 50%, and more particularly from 10% to 45% by weight relative to the weight. total of the composition. Liquid Fatty Phase A cosmetic composition according to the present invention may comprise at least one liquid fatty phase and especially at least one oil as mentioned below. The term "oil" means any fatty substance in liquid form at ambient temperature (20-25 ° C.) and at atmospheric pressure.
[0045] A composition of the invention may comprise a liquid fatty phase in a content ranging from 1 to 90%, in particular from 5 to 80%, in particular from 10 to 70%, and more particularly from 20 to 50% by weight per relative to the total weight of the composition. The oily phase suitable for the preparation of the cosmetic compositions according to the invention may comprise, in addition to the aforementioned oils in relation to the vinyl polymer grafted with a carbosiloxane dendrimer, hydrocarbon oils, silicone oils, fluorinated or not, or mixtures thereof. Preferably, the composition of the invention comprises at least one silicone oil.
[0046] The oils can be volatile or nonvolatile. They can be of animal, vegetable, mineral or synthetic origin. For the purposes of the present invention, the term "volatile oil" means an oil (or non-aqueous medium) capable of evaporating on contact with the skin in less than one hour, at ambient temperature and at atmospheric pressure. The volatile oil is a volatile cosmetic oil which is liquid at ambient temperature, in particular having a non-zero vapor pressure, at ambient temperature and at atmospheric pressure, in particular, having a vapor pressure ranging from 0.13 Pa to 40,000 Pa (101 to 300 mm Hg), and preferably ranging from 1.3 Pa to 13 000 Pa (0.01 to 100 mm Hg), and preferably ranging from 1.3 Pa to 1300 Pa (0.01 to 100 mm Hg), and preferably ranging from 1.3 Pa to 1300 Pa (0.01 to 100 mm Hg), and preferably ranging from 1.3 Pa to 1300 Pa (0.01 to 100 mm Hg), mm Hg). For the purposes of the present invention, the term "non-volatile oil" means an oil having a vapor pressure of less than 0.13 Pa.
[0047] For the purposes of the present invention, the term "silicone oil" means an oil comprising at least one silicon atom, and in particular at least one Si-O group. The term "fluorinated oil" means an oil comprising at least one fluorine atom. The term "hydrocarbon oil" means an oil containing mainly hydrogen and carbon atoms. The oils may optionally comprise oxygen, nitrogen, sulfur and / or phosphorus atoms, for example in the form of hydroxyl or acid radicals. Volatile oils The volatile oils may be chosen from hydrocarbon-based oils containing from 8 to 16 carbon atoms, and especially branched C8-C16 alkanes (also known as isoparaffins), such as isododecane (also called 2,2,4,4 , 6-pentamethylheptane), isodecane, isohexadecane, and, for example, the oils sold under the trade names ISOPARS® or PERMETHYLS®.
[0048] Volatile silicones, such as, for example, volatile linear or cyclic silicone oils, in particular those having a viscosity of 8 centistokes (cSt) (8 × 10 -6 m 2 / s), and having in particular, from 2 to 10 silicon atoms, and in particular from 2 to 7 silicon atoms, these silicones optionally containing alkyl or alkoxy groups having from 1 to 10 carbon atoms. As the volatile silicone oil that may be used in the invention, mention may be made, in particular, of dimethicones of viscosity 5 and 6 cSt, octamethyl cyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, heptamethylhexyltrisiloxane, heptamethyloctyltrisiloxane, hexamethyl disiloxane, octamethyl trisiloxane, decamethyl tetrasiloxane, dodecamethyl pentasiloxane, and mixtures thereof.
[0049] It is also possible to use fluorinated volatile oils, such as nonafluoromethoxybutane or perfluoromethylcyclopentane, and mixtures thereof.
[0050] According to one embodiment, a composition of the invention may comprise from 1% to 80% by weight, or even from 5% to 70% by weight, or even from 10% to 60% by weight, and in particular from 15% to 50% by weight. % by weight of volatile oils relative to the total weight of the composition, this content taking into account the volatile oil conveying the vinyl polymer with a carbosiloxane dendrimer motif. Nonvolatile oils Nonvolatile oils may, in particular, be chosen from hydrocarbon oils, fluorinated oils and / or nonvolatile silicone oils.
[0051] Non-volatile hydrocarbon oils that may especially be mentioned include: - hydrocarbon-based oils of animal origin, such as perhydrosqualene; - hydrocarbon-based oils of plant origin, such as phytostearyl esters, such as phytostearyl oleate, isostearate of physostearyl and lauroyl glutamate / octyldodecyl / phytostearyl (AJINOMOTO, ELDEW PS203), triglycerides consisting of esters of fatty acids and glycerol, in particular, whose fatty acids may have chain lengths varying from C4 at C36, and especially from C18 to C36, these oils being linear or branched, saturated or unsaturated; these oils may, in particular, be heptanoic or octanoic triglycerides, shea, alfalfa, poppy, pumpkin, millet, barley, quinoa, rye, bancoulier, passionflower oil, butter shea butter, aloe oil, sweet almond oil, peach almond oil, peanut oil, argan oil, avocado oil, oil of baobab, borage oil, broccoli oil, calendula oil, camelina oil, canola oil, carrot oil, safflower oil, hemp oil , rapeseed oil, cottonseed oil, coconut oil, pumpkin seed oil, wheat germ oil, jojoba oil, lily oil, oil of macadamia, corn oil, meadowfoam oil, St. John's wort oil, monoi oil, hazelnut oil, apricot kernel oil, walnut oil, olive oil, evening primrose oil, palm oil, blackcurrant seed oil, kiwifruit seed oil, pomace oil Grape, Pistachio Oil, Pumpkin Oil, Pumpkin Oil, Quinoa Oil, Rosehip Oil, Sesame Oil, Soybean Oil, Sunflower Oil , castor oil, and watermelon oil, and mixtures thereof, or caprylic / capric acid triglycerides, such as those sold by Stearineries Dubois or those sold under the names MIGLYOL 810®, 812® and 818® by the company DYNAMIT NOBEL, - linear or branched hydrocarbons of mineral or synthetic origin such as paraffin oils and their derivatives, petroleum jelly, polydecenes, polybutenes, hydrogenated polyisobutene such as Parleam, squalane ; synthetic ethers having from 10 to 40 carbon atoms; synthetic esters, such as the oils of formula RiCOOR 2, in which R 1 represents a residue of a linear or branched fatty acid comprising from 1 to 40 carbon atoms, and R 2 represents a hydrocarbon chain, in particular, branched, containing from 1 to 40 carbon atoms provided that R1 + R2 is 10. The esters may be, in particular, chosen from alcohol and fatty acid esters, for example: cetostearyl octanoate, esters of isopropyl alcohol such as isopropyl myristate, isopropyl palmitate, ethyl palmitate, 2-ethylhexyl palmitate, isopropyl isostearate or isostearate, isostearyl isostearate, sodium stearate, octyl, hydroxyl esters, such as isostearyl lactact, octyl hydroxystearate, diisopropyl adipate, heptanoates, and especially isostearyl heptanoate, octanoates, decanoates or ricinoleates of alcohols or polyalcohols such as propylene glycol dioctanoate cetyl octanoate, tridecyl octanoate, 4-diheptanoate and 2-hexyl ethyl palmitate, alkyl benzoate, polyethylene glycol diheptanoate, propylene glycol diethyl-2-hexanoate, and mixtures thereof. , C12-C15 alcohol benzoates, hexyl laurate, esters of neopentanoic acid, such as isodecyl neopentanoate, isotridecyl neopentanoate, isostearyl neopentanoate, octyldocecyl neopentanoate, esters of isononanoic acid, such as isononyl isononanoate, isotridecyl isononanoate, octyl isononanoate, hydroxyl esters such as isostearyl lactate, di-isostearyl malate; esters of polyols and esters of pentaerythritol, such as dipentaerythritol tetrahydroxystearate / tetraisostearate; esters of diol dimers and of diacid dimers, such as Lusplan DD-DA5® and Lusplan DD-DA7, marketed by the company Nippon FINE CHEMICAL and described in the application US 2004-175338, - copolymers of diol dimer and dimer diacid and their esters, such as dimeric copolymers dilinoleyl diol / dimer dilinoleic and their esters, such as for example Plandool-G, - copolymers of polyols and diacid dimers, and their esters, such as Hailuscent ISDA, or dilinoleic acid / butanediol copolymer, - branched-chain and / or unsaturated carbon-chain liquid fatty alcohols having from 12 to 26 atoms of carbon, such as 2-octyldodecanol, isostearyl alcohol, oleic alcohol, 2-hexyldecanol, 2-butyloctanol, and 2-undecylpentadecanol, - higher fatty acids C 12 -C 22, such as oleic acid, linoleic acid, linolenic acid, and mixtures thereof, and di-alkyl carbonates, the 2 alkyl chains being identical or different, such as dicaprylyl; carbonate sold under the name CETIOL CC®, by COGNIS, - oils of high molar mass having, in particular, a molar mass ranging from about 400 to about 10,000 g / mol, in particular from about 650 to about 10 000 g / mol, in particular from about 750 to about 7500 g / mol, and more particularly from about 1000 to about 5000 g / mol. As oil of high molar mass that can be used in the present invention, mention may be made especially of oils chosen from: lipophilic polymers, linear fatty acid esters having a total carbon number ranging from 35 to 70, hydroxyl esters aromatic esters, esters of fatty alcohols or branched C24-C28 fatty acids, silicone oils, oils of vegetable origin, and mixtures thereof. fluorinated oils that may be partially hydrocarbon-based and / or silicone-based, such as fluorosilicone oils, fluorinated polyethers or fluorinated silicones, as described in document EP-A-847,752; silicone oils, such as non-volatile, linear or cyclic polydimethylsiloxanes (PDMS); polydimethylsiloxanes comprising alkyl, alkoxy or phenyl groups, during or at the end of the silicone chain, groups having from 2 to 24 carbon atoms; phenyl silicones such as phenyl trimethicones, phenyl dimethicones, phenyl trimethylsiloxy diphenyl siloxanes, diphenyl dimethicones, diphenyl methyldiphenyl trisiloxanes, 2-phenylethyl trimethylsiloxysilicates and their mixtures. According to a particular embodiment, the fatty phase of the composition according to the invention may contain only volatile compounds. Advantageously, and as indicated above, a composition according to the invention may comprise at least one silicone oil or a mixture of silicone oil (s). According to one particular embodiment, the composition of the invention comprises at least one volatile silicone oil, preferably dodecamethylpentasiloxane.
[0052] Advantageously, a cosmetic composition according to the present invention may also comprise at least one volatile hydrocarbon oil, chosen from isododecane, isohexadecane and mixtures thereof. Lipophilic structuring agent A composition according to the invention, in particular when it is an eyeshadow composition, may further comprise at least one structuring agent of liquid fatty phase chosen from a wax, a pasty compound, and their mixtures. In particular, a wax that is suitable for the invention may especially be chosen from waxes of animal, vegetable, mineral, and synthetic origin, and mixtures thereof.
[0053] As examples of waxes that can be used according to the invention, mention may be made of waxes of animal origin, such as beeswax, spermaceti, lanolin wax and lanolin derivatives, and vegetable waxes such as Carnauba wax, Candelilla wax, Ouricury wax, Japan wax, cocoa butter or cork fiber wax or sugar cane wax, - mineral waxes, eg paraffin wax, petroleum jelly, lignite wax or microcrystalline waxes or ozokerites; synthetic waxes, among which polyethylene waxes, and waxes obtained by Fisher-Tropsch synthesis; silicone waxes, in particular substituted linear polysiloxanes; mention may be made, for example, of polyether silicone waxes, alkyl or alkoxy dimethicones having from 16 to 45 carbon atoms, alkyl methicones such as C30-C45 alkylmethicone sold under the trade name "AMS C 30" by DOW CORNING, hydrogenated oils that are concrete at 25 ° C such as hydrogenated castor oil, hydrogenated jojoba oil, hydrogenated palm oil, hydrogenated tallow, hydrogenated coconut oil and concrete fatty esters with 25 ° C., such as the C 20 -C 40 alkyl stearate sold under the trade name Kester WAX K82H by the company K0S TER KEUNEN, and / or their mixtures. Preferably, use will be made of polyethylene waxes, microcrystalline waxes, carnauba waxes, hydrogenated jojoba oil, candellila waxes, beeswaxes, ozokerites and / or mixtures thereof. The structuring agent (s) may be present in a composition of the invention in a content ranging from 0.1 to 30% by weight of agents, more preferably from 0.5 to 20% by weight, relative to the total weight of the composition. THICKENING AGENTS According to the fluidity of the composition that it is desired to obtain, one or more thickening or gelling agents may be incorporated in a composition of the invention. A thickening or gelling agent suitable for the invention may be hydrophilic, that is to say soluble or dispersible in water. As hydrophilic gelling agents, mention may in particular be made of water-soluble or water-dispersible thickening polymers. These may especially be chosen from: carboxyvinyl polymers modified or not, such as the products sold under the names Carbopol (CTFA name: carbomer) by the company Goodrich; polyacrylates and polymethacrylates such as the products sold under the names Lubrajel and Norgel by the company GUARDIAN or under the name Hispagel by the company HISPANO CHIMICA; polyacrylamides; polymers and copolymers of 2-acrylamido-2-methylpropanesulphonic acid, optionally crosslinked and / or neutralized, such as poly (2-acrylamido-2-methylpropanesulphonic acid) sold by Clariant under the name "Hostacerin AMPS" (CTFA name ammonium polyacryldimethyltauramide); crosslinked anionic copolymers of acrylamide and of AMPS, in the form of an W / O emulsion, such as those marketed under the name SEPIGEL 305 (CTFA name: Polyacrylamide / C13-14 Isoparaffin / Laureth-7) and under the name SIMUILGEL 600 (CTFA name: Acrylamide / Sodium acryloyldimethyltaurate copolymer / Isohexadecane / Polysorbate 80) by the company SEPPIC; polysaccharide biopolymers such as xanthan gum, guar gum, locust bean gum, acacia gum, scleroglucans, chitin and chitosan derivatives, carrageenans, gellanes, alginates, celluloses such as microcrystalline cellulose, carboxymethylcellulose, hydroxymethylcellullose and hydroxypropylcellulose; and their mixtures. A thickening or gelling agent that is suitable for the invention may be lipophilic. It can be mineral or organic. Examples of lipophilic thickening agents that may be mentioned are modified clays, such as modified magnesium silicate (Bentone gel VS38 from Rheox), modified hectorites such as hectorite modified with a C10 fatty acid ammonium chloride, C22, such as hectorite modified with di-stearyl dimethyl ammonium chloride such as, for example, that sold under the name Bentone 38V® by the company ELEMENTIS or that marketed under the name "Bentone 38 CE" by the RHEOX company or that marketed under the name Bentone Gel V5 5V by the company ELEMENTIS. Among the lipophilic gelling agents that can be used in a cosmetic composition of the invention, mention may also be made of dextrin and fatty acid esters, such as dextrin palmitates, in particular such as those sold under the names Rheopearl TL® or Rheopearl KL® by the company CHIBA FLOUR, hydrogenated vegetable oils, such as hydrogenated castor oil, fatty alcohols, in particular C8 to C26 alcohols, and more particularly C12 to C22 alcohols, for example, mysrityl alcohol, cetyl alcohol, stearyl alcohol or behenyl alcohol.
[0054] According to one embodiment, a composition of the invention may comprise thickening agents with an active material content of from 0.01% to 40% by weight, in particular from 0.1% to 20% by weight, in particular from 0%, 3 to 15% by weight relative to the total weight of the composition. COLORING USES A composition according to the invention may further comprise at least one dyestuff. A cosmetic composition in accordance with the invention may advantageously incorporate at least one dyestuff chosen from organic or inorganic dyestuffs, in particular of the type of pigment or nacre conventionally used in cosmetic compositions, fat-soluble or water-soluble dyes, specific optical effect and their mixtures. The term "pigments" is intended to mean white or colored particles, mineral or organic, insoluble in an aqueous solution, intended to color and / or opacify the resulting film. The pigments may be present in a proportion of from 0.1 to 40% by weight, in particular from 1 to 30% by weight, and in particular from 5 to 15% by weight, relative to the total weight of the cosmetic composition.
[0055] As inorganic pigments that may be used in the invention, mention may be made of titanium, zirconium or cerium oxides, as well as zinc, iron or chromium oxides, ferric blue, manganese violet, ultramarine blue and Chromium hydrate. It may also be a pigment having a structure which may for example be sericite / brown iron oxide / titanium dioxide / silica. Such a pigment is marketed for example under the reference COVERLEAF NS or JS by CHEMICALS AND CATALYSTS and has a contrast ratio of about 30. The dyestuff may further comprise a pigment having a structure which may be, for example, type microspheres of silica containing iron oxide. An example of a pigment having this structure is that marketed by MIYOSHI under the reference PC BALL PC-LL-100 P, this pigment consisting of silica microspheres containing yellow iron oxide.
[0056] Among the organic pigments that can be used in the invention, mention may be made of carbon black, D & C type pigments, cochineal carmine, barium, strontium, calcium, aluminum or diketo pyrrolopyrrole (DPP) lacquers. ) described in EP-A-542 669, EP-A-787 730, EP-A-787 731 and WO-A-96/08537.
[0057] By "nacres", it is necessary to include colored particles of any shape, iridescent or otherwise, in particular, produced by certain shellfish in their shell or else synthesized and which exhibit a color effect by optical interference. The nacres can be chosen from pearlescent pigments, such as titanium mica coated with an iron oxide, titanium mica coated with bismuth oxychloride, titanium mica coated with chromium oxide, titanium mica coated with with an organic dye, as well as pearlescent pigments based on bismuth oxychloride. It may also be mica particles on the surface of which are superimposed at least two successive layers of metal oxides and / or organic dyestuffs.
[0058] Mention may also be made, by way of example of nacres, of natural mica coated with titanium oxide, with iron oxide, with natural pigment or with bismuth oxychloride. Among the nacres available on the market, mention may be made of the TIMICA, FLAMENCO and DUOCHROME pearls (based on mica) marketed by ENGELHARD, the TIMIRON pearls marketed by MERCK, and the nacres 20 based on PRESTIGE mica marketed by the company. company ECKART and nacres based on synthetic mica SUNSHINE marketed by the company SUN CHEMICAL. The nacres may more particularly have a color or a yellow, pink, red, bronze, orange, brown, gold and / or coppery reflection. As an illustration of the nacres that can be used in the context of the present invention, it is possible, in particular, to mention gold-colored nacres, in particular sold by Engelhard under the name Brillant gold 212G (Timica), Gold 222C (Cloisonne), Sparkle gold (Timica), Gold 4504 (Chromalite) and Monarch gold 233X (Cloisonne); bronze nacres, in particular, sold by the company Merck under the name Bronze Fine (17384) (Colorona) and Bronze (17353) 30 (Colorona) and by Engelhard under the name Super Bronze (Cloisonne); orange nacres, in particular, sold by ENGELHARD under the name Orange 363C (Cloisonne) and Orange MCR 101 (Cosmica) and by MERCK under the name Passion orange (Colorona) and Matte orange (17449) (Microna); brown-colored pearlescent agents, in particular, sold by ENGELHARD under the name Nu-antique copper 340XB (Cloisonne) and Brown CL4509 (Chromalite); nacres with a copper sheen, in particular, marketed by Engelhard under the name Copper 340A (Timica); the red-colored pearlescent agents, in particular, marketed by MERCK under the name Sienna fine (17386) (Colorona); yellow-colored pearlescent agents, in particular, marketed by Engelhard under the name Yellow (4502) (Chromalite); nacres of red hue with gold glare, in particular, sold by ENGELHARD under the name Sunstone G012 (Gemtone); pink nacres, in particular, sold by ENGELHARD under the name Tan opal G005 (Gemtone); black nacres with gold reflection, sold by the company Engelhard under the name Nu antique bronze 240 AB (Timica), blue pearls, in particular, sold by MERCK under the name Matte Blue (17433) (Microna), white nacres with silvery reflection, in particular, sold by the company Merck under the name Xirona Silver and the golden-green orange-colored mother-of-pearl, in particular, marketed by MERCK under the name Indian summer (Xirona) and their mixtures. The cosmetic composition according to the invention may also comprise water-soluble or fat-soluble dyes. Liposoluble dyes are, for example, Sudan Red, DC Red 17, DC Green 6, (3-carotene, soybean oil, Sudan Brown, DC Yellow 11, DC Violet 2, DC orange 5 and quinoline yellow The water-soluble dyes are, for example, beet juice and caramel.
[0059] ADDITIVES A cosmetic composition according to the invention may also comprise any additive usually used in the field concerned, for example chosen from gums, anionic, cationic, amphoteric or nonionic surfactants, silicone surfactants, gums, resins, dispersing agents, semi-crystalline polymers, antioxidants, essential oils, preservatives, perfumes, neutralizers, antiseptics, UV protective agents, cosmetic or dermatological active agents, such as vitamins , moisturizing agents, emollients or collagen protectors, desquamating agents, barrier agents, depigmenting agents, antioxidants, anti-acne agents, soothing agents, anti-inflammatory agents and mixtures thereof.
[0060] It falls within the routine operations of a person skilled in the art to adjust the nature and the quantity of the additives present in the compositions in accordance with the invention, so that the cosmetic properties, in particular the dullness and its behavior in the time, and the desired stability properties of these are not affected. A composition according to the invention may, in particular, be in the form of a makeup composition and / or care of the skin, lips or eyebrows, especially a foundation or makeup base. Throughout the description, including the claims, the phrase "having one" should be understood as being synonymous with "having at least one", unless the opposite is specified. Expressions "between ... and ..." and "ranging from ..." must be understood as inclusive terms, unless otherwise specified. The examples and figures which follow are presented by way of illustration and not limitation of the invention. EXAMPLES Example 1 Influence of the Nature of the Polymer on the Maturity Performance General formula of Example 1 (Fluid Foundation) Phase Compounds Example 1A (Invention) Example 1B Example 1C (comparative) (comparative) Al BIS-PEG / PPG-14/14 100 100 100 DIMETHICONE (and) DIMETHICONE sold under the reference ABIL EM 97S by the company EVONIK GOLDSCHMIDT Isododecane 0.00 12.5 5.50 Isohexadecane 6.50 6.50 6.50 PEG-10 DIMETHICONE sold under 2.50 2.50 2.50 reference KF-6017 by SHIN ETSU ACRYLATES / 12.50 0.00 0.00 POLYTRIMETHYLSILOXY - (ie 5% in METHACRYLATE COPOLYMER material sold under the DOW active reference) CORNING FA 4002 ID SILICONE ACRYLATE by the company Dow Corning (40% active ingredient) Resin Tpropyl 0 00 0 00 6.9 POLYPROPYLSILSESQUIOXANE ,, (or 5% in (and ) ISODODECANE sold under the reference DOW CORNING 680 ID active) FLUID p by DOW CORNING company (72.5-77.5% active ingredient) Qs DIMETHICONE sold under the Qs 100 Qs 100 Qs 100 reference DM-FLUID 2 CS by the company SHIN ETSU A2 DISTEARDIMONIUM HECTORITE 0.35 0.35 0, 35 sold under the reference BENTONE 38 VCG by the company ELEMENTIS A3 Iron oxides and titanium 13.00 13.00 13.00 A4 NYLON-12 sold under the reference 7.00 7.00 7.00 ORGASOL 2002 EXD NAT COS by the company ARKEMA Silica sold under the reference 3.00 3.00 3.00 SUNSPHERE H51 AGC by SI-TECH ACRYLATES COPOLYMER sold 0.50 0.50 0.50 under the reference EXPANCEL 551 DE 40 D42 by AKZO NOBEL B1 WATER 32.00 32.00 32.00 B2 GLYCOL 4.00 4.00 4.00 PHENOXYETHANOL 1.20 1.20 1.20 Operating Procedure: The constituents of phase B2 are weighed in a 500 ml beaker. In parallel, bring to a boil B1 then add B1 in B2. Magnetically stir to cool.
[0061] In a 1L beaker, weigh Al and stir Morritz. In a capsule, weigh A2 then add A2 in Al. In one capsule, weigh A3 + 50% Al. Grind 3 times in a three-roll then add the rest of Al + A2. Weigh the A4 charges separately and introduce them one at a time allowing to homogenize 5 min minimum between each. The emulsion is carried out at ambient temperature: the mixture B1 and B2 are poured into the fatty phase by progressively increasing the stirring speed (Moritz). Stirring is maintained for 10 minutes. Measurement of Maturity and Maturity Performance Maturity and mattness performance are evaluated on a panel of 7 women (A to G) according to the protocol detailed previously in the description. Reference Example 1A was rated as dull at TO and holding very well after 3 hours on the face. The level of dullness after 3 hours is considered equal to that of TO. It was asked to judge the performance in terms of dullness and mattness of compositions B and C in half-face compared to Example 1A of reference. The differences are noted with 1 or 2+ if the immediate dullness or the behavior of dullness at 3 o'clock is better and lou 2- otherwise. The results obtained with the compositions IA to C are given in Table 1 below.
[0062] Table 1 Example 1 Example 1B Example 1C (Invention) (Comparative) (Comparative) Maturity TO T3h TO T3h TO T3h A 0 0 = - - B 0 0 = - - C 0 0 = - - D 0 0 = - - E 0 0 - F 0 0 = - - G 0 0 = - __ The foundation fluid lA (according to the invention) show improved performance in terms of the behavior of dullness compared to funds complexion 1B and 1C (comparative). In fact, the vinyl polymer having at least one unit derived from carbosiloxane dendrimer (1A) is superior to other polymers (1B and 1C) with respect to the behavior of dullness. What is more, the composition IA is pleasant and easy to apply, while maintaining satisfactory application comfort, that is to say not having a feeling of tightness or effect mask throughout the day and / or does not induce a feeling of greasy or sticky during its application.
[0063] EXAMPLE 2 Influence of the Nature of the Filler on the Maturity Performance General Formulation of Example 2 (Fluid Foundation) Phase Compounds Example 2A Example 2B Example 2C (Invention) (Comparative) (Comparative) Al BIS-PEG / PPG-14/14 1,00 1,00 1,00 DIMETHICONE (and) DIMETHICONE sold under the reference ABIL EM 97 S by the company EVONIK GOLDSCHMIDT Isohexadecane 6.50 6.50 6.50 PEG-10 DIMETHICONE sold under 2, 50 2.50 2.50 the reference KF-6017 by the company SHIN ETSU ACRYLATES / 12.50 12.50 12.50 POLYTRIMETHYLSILOXY- (that is 5% in (or 5% in (or 5% in METHACRYLATE COPOLYMER matter matter material) sold under the reference DOW active) active) CORNING FA 4002 ID SILICONE active) ACRYLATE by the company Dow Corning (40% active ingredient) Qs DIMETHICONE sold under the Qs 100 Qs 100 Qs 100 reference DM-FLUID 2 CS by the company SHIN ETSU A2 DISTEARDIMONIUM HECTORITE 0.35 0.35 0.35 sold under the reference BENTONE 38VCG by the company ELEMENTIS A3 Iron oxides t titanium 13.00 13.00 13.00 A5 NYLON-12 sold under the reference 7.00 7.25 7.10 ORGASOL 2002 EXD NAT COS by the company ARKEMA Silica sold under the reference 3.00 3.25 3, 10 SUNSPHERE H51 by the company ARKEMA ACRYLATES COPOLYMER sold 0.50 0.00 0.30 under the reference EXPANCEL 551 DE 40 D42 by the company AKZO NOBEL B1 WATER 32.00 32.00 32.00 B2 GLYCOL 4.00 4, 00 4.00 PHENOXYETHANOL 1.20 1.20 1.20 Example 2A is identical to Example 1A and prepared in the same way.
[0064] Measurement of the dullness and the resistance of the dullness This measurement is as described in example 1 above. The results obtained with compositions 2A to C are given in Table 2 below.
[0065] Table 2 Example 2A Example 2B Example 2C (Invention) (Comparative) (Comparative) Matter TO T3h TO T3h TO T3h A 0 0 = - - B 0 0 = - - C 0 0 = - - D 0 0 = - - E 0 0 = - F 0 0 - G 0 0 = - - The foundation fluid 2A (according to the invention) shows improved performance in terms of the resistance of dullness compared to foundations 2B and 2C (comparative). In fact, the presence of Expancel particles in a specific content of at least 0.5% by weight (2A) is necessary to obtain properties in terms of dullness and the durability of the dullness. Moreover, since the composition 2A is in fact identical to the composition 1A of Example 1, the same comments concerning the application and comfort properties can be repeated.
[0066] In view of the foregoing, it appears that it is the Expancel combination (at least 0.5% by weight) + vinyl polymer having at least one unit derived from carbosiloxane dendrimer which makes it possible to obtain a cosmetic effect improved, namely a significant mattness.
[0067] The shades of the composition of Example 1A described above can be adapted depending on the application, on the skin of the face or the eyebrows, by varying the rate of iron oxides (especially black) and of titanium oxides. A composition of the invention as described in Example 1 with a pigment level adjusted to the desired shade, can thus constitute an eyebrow makeup product with an immediate and permanent dullness.
[0068] Example 3: Eyeshadow composition Phase Compounds Example Al BIS-PEG / PPG-14/14 DIMETHICONE (and) 100 DIMETHICONE sold under the reference ABIL EM 97 S by the company EVONIK GOLDSCHMIDT Isododecane 2,5 PEG-10 DIMETHICONE sold under 250 KF-6017 reference by SHIN ETSU ACRYLATES / 12.50 (or 5% POLYTRIMETHYLSILOXY- active) METFIACRYLATE COPOLYMER sold under the reference DOW CORNING FA 4002 ID SILICONE ACRYLATE by the company Dow Corning (40% active ingredient) ) Al DIMETHICONE sold under the reference Qs 100 DM-FLUID 2 CS by the company SHIN ETSU A2 DISTEARDIMONIUM HECTORITE sold 0.35 under the reference BENTONE 38VCG by the company ELEMENTIS A3 Iron oxides and titanium 13.00 A4 NYLON-12 sold under the reference 7,00 ORGASOL 2002 EXD NAT COS by the company ARKEMA Silica sold under the reference SUNSPHERE 300 H51 by the company ARKEMA ACRYLATES COPOLYMER sold under the 0.50 reference EXPANCEL 551 DE 40 D42 by the company AKZO NOBEL B1 WATER 32.00 B2 GLYCOL 4.00 PHENOXYETHANOL 1.20 C OZOKERITE 6.50 STEARYL ALCOHOL 10 Isohexadecane 6 Operating Procedure: The constituents of phase B2 are weighed in a 500 ml beaker. In parallel, bring to a boil B1 then add B1 in B2. Magnetically stir to cool.
[0069] In a 1L beaker, weigh Al and stir Morritz. In one capsule, weigh A2 then add A2 in Al. In one capsule, weigh A3 + 50% Al. Grind 3 times in a three-roll then add the rest of A 1 + A2. Weigh the A4 charges separately and introduce them one at a time allowing to homogenize 5 min minimum between each. The emulsion is carried out at ambient temperature: the mixture B1 and B2 are poured into the fatty phase by progressively increasing the stirring speed (Moritz). Stirring is continued for 10 minutes. Meanwhile, phase C is melted in a water bath at 60 ° C. Allow to cool to 40 ° C. and introduce into the emulsion with stirring. Maintain agitation for 10 min. The final product is a solid composition which, applied on the eyelids, gives a fine makeup result with properties of immediate dullness and improved dullness over time.
[0070] Example 4: Skincare or make-up base Phase Compounds Example (Invention) Al BIS-PEG / PPG-14/14 DIMETHICONE (and) 115 DIMETHICONE sold under the reference ABIL EM 97 S by the company EVONIK GOLDSCHMIDT Isohexadecane 7.45 PEG-10 DIMETHICONE sold under the 2.85 reference KF-6017 by the company SHIN ETSU ACRYLATES / POLYTRIMETHYLSILOXYMETFIACRYLATE COPOLYMER sold under the reference DOW CORNING FA 4002 14.35 (or 574% active ingredient) ID SILICONE ACRYLATE by the company Dow Corning (40% active ingredient) DIMETHICONE sold under the reference Qs 100 DM-FLUID 2 CS by the company SHIN ETSU A2 DISTEARDIMONIUM HECTORITE sold 0.40 under the reference BENTONE 38VCG by the company ELEMENTIS A3 Oxides of iron and titanium 0 A4 NYLON-12 sold under the reference 8.05 ORGASOL 2002 EXD NAT COS by the company ARKEMA Silica sold under the reference SUNSPHERE 3.45 H51 by the company ARKEMA ACRYLATES COPOLYMER sold under the 0.55 reference EXPANCEL 551 DE 40 D42 by the company AKZO NOBEL B1 WATER 36.8 B2 GLYCOL 4.60 PHENOXYETHANOL 1.40 This composition is prepared according to the protocol described in Example 1. Applied on the skin of the face before a make-up product (eg foundation), it improves the appearance of the skin. Matte rendering of makeup and holding dullness in time.

权利要求:
Claims (17)
[0001]
REVENDICATIONS1. Cosmetic composition for the make-up and / or care of keratin materials, in particular the skin, in the form of a water-in-oil emulsion comprising, in a physiologically acceptable medium, at least one vinyl polymer having at least one motif carbosiloxane dendrimer derivative, and at least 0.5% by weight of expanded polymer particles relative to the total weight of the composition.
[0002]
The composition of claim 1, wherein the expanded polymer particles are selected from thermoplastic material particles selected from polymers or copolymers of acrylonitrile, vinylidene chloride, vinyl chloride and / or acrylic or styrenic monomer. , possibly expanded.
[0003]
A composition according to any one of the preceding claims, wherein the expanded polymer particles are selected from hollow particles of an expanded copolymer of vinylidene chloride and acrylonitrile, or vinylidene chloride, acrylonitrile and methyl methacrylate.
[0004]
4. Composition according to any one of the preceding claims, said composition comprising from 0.5 to 5% by weight of expanded polymer particles relative to the total weight of the composition, in particular from 0.5 to 2.5%, and more particularly from 0.5 to 1.5% by weight relative to the total weight of the composition.
[0005]
A composition according to any one of the preceding claims, wherein the vinyl polymer having at least one carbosiloxane dendrimer derived unit has a side molecular chain containing a carbosiloxane dendrimer structure and is derived from the polymerization of: (A) from 0 99.9 parts by weight of a vinyl monomer; and (B) from 100 to 0.1 parts by weight of a carbosiloxane dendrimer of the following formula (I): Y-Si-R 1 O-Si-X '(I) 3 wherein: - Ri represents an aryl group of 5 to 10 carbon atoms or an alkyl group of 1 to 10 carbon atoms; - Xi represents a silylalkyl group which, when i = 1, is represented by the formula (II): (OR3) al R2 Si O Si XI + R '3-a' in which: Ri is as defined above in formula (I), R2 represents an alkylene radical of 2 to 10 carbon atoms, R3 represents an alkyl group of 1 to 10 carbon atoms, Xi + i is chosen from: a hydrogen atom, an alkyl group of 1 to 10 carbon atoms, an aryl group of 5 to 10 carbon atoms and a silylalkyl group defined above of formula (II) with i = i + 1,. i is an integer from 1 to 10 which represents the generation of said silylalkyl group, and ai is an integer from 0 to 3; Y represents an organic group polymerizable with radicals chosen from: organic groups containing a methacrylic group or an acrylic group, said organic groups being represented by the following formulas: ## STR1 ## in which: R 4 represents a hydrogen atom or an alkyl group of 1 to 10 carbon atoms; and * R5 represents an alkylene group of 1 to 10 carbon atoms; and. styryl group-containing organic groups of the formula: wherein: R 6 represents a hydrogen atom or an alkyl group of 1 to 10 carbon atoms; R7 represents an alkyl group of 1 to 10 carbon atoms; R8 represents an alkylene group of 1 to 10 carbon atoms; * b is an integer from 0 to 4; and * c is 0 or 1, so that if c is 0, - (R), - represents a bond.
[0006]
6. A composition according to any one of the preceding claims, wherein the carbosiloxane dendrimer is represented by the following formula: (OR3) 1 (Oa3) a2 Ri Y Si I 2 al I 2 2 a3 Si R12 O Si R Si O Si R Si O Si R Si O R 1 Ri Ri 3-a 3 3-a 2 3 -al 3 in which: Y, R 1, R 2 and R 3 are as defined in claim 5; . al, a2 and a3 are as defined in claim 5; and. R'2 is H, an aryl group of 5 to 10 carbon atoms or an alkyl group of 1 to 10 carbon atoms.
[0007]
A composition according to any one of the preceding claims, wherein the carbosiloxane dendrimer is represented by one of the following formulas: ## STR1 ## ## STR1 ##
[0008]
8. Composition according to any one of the preceding claims, wherein said vinyl polymer having at least one carbosiloxane dendrimer derived unit is present in an active ingredient content ranging from 3% to 15% by weight relative to the total weight of the composition. , in particular ranging from 4% to 10% by weight, and more particularly ranging from 5% to 8% by weight of vinyl polymer active material having at least one unit derived from carbosiloxane dendrimer.
[0009]
9. Composition according to any one of the preceding claims, comprising a weight ratio "vinyl polymer (s) having at least one carbosiloxane dendrimer derivative / expanded polymer particles" greater than or equal to 6, preferably greater than or equal to at 8, more particularly greater than or equal to
[0010]
10. Composition according to any one of the preceding claims, characterized in that it further comprises at least one additional filler, preferably chosen from mattifying or absorbing sebum fillers.
[0011]
11. Composition according to the preceding claim, characterized in that the additional filler is an organic filler, in particular chosen from polyamide powders, optionally combined with a mineral filler such as silica.
[0012]
12. Composition according to any one of the preceding claims, characterized in that the total filler content (s), especially when the composition comprises additional charges distinct from the expanded polymer particles, ranges from 3 to 20% by weight. weight relative to the total weight of the composition, preferably 8 to 15% by weight, or even 10 to 15% by weight relative to the total weight of said composition.
[0013]
13. Composition according to any one of the preceding claims, comprising a weight ratio "vinyl polymer (s) having at least one derivative of carbosiloxane dendrimer / total charges", especially when the composition comprises additional charges distinct from the particles of expanded polymers, less than 1, preferably less than 0.6, and more preferably less than 0.5.
[0014]
14. Composition according to any one of the preceding claims, further comprising at least one dyestuff.
[0015]
15. Composition according to any one of the preceding claims, said composition being a skincare or makeup base, or a makeup product for keratin materials, in particular the skin, the lips or the eyebrows, in particular a backing. complexion, a hot-melt foundation product, a lipstick, a body make-up product, a concealer, an eyeshadow or an eyebrow product.
[0016]
16. Use in a cosmetic composition, especially of water-oil-type, makeup and / or care of keratin materials, of at least one vinyl polymer having at least one unit derived from carbosiloxane dendrimer in combination with at least 0.5 % by weight of expanded polymer particles relative to the total weight of the composition to impart to said composition a durability of the improved dullness.
[0017]
17. A method for making and / or non-therapeutic care of keratinous substances, in particular the skin comprising at least the step of applying to said keratinous material at least one layer of a composition according to any one of claims 1 at 15.

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法律状态:
2015-11-10| PLFP| Fee payment|Year of fee payment: 3 |

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2016-11-11| PLFP| Fee payment|Year of fee payment: 4 |

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2017-11-13| PLFP| Fee payment|Year of fee payment: 5 |

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2019-09-27| ST| Notification of lapse|Effective date: 20190906 |

优先权:

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申请号 | 申请日 | 专利标题

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FR1363253A|FR3015251B1|2013-12-20|2013-12-20|COSMETIC COMPOSITION COMPRISING A CARBOSILOXANE DENDRIMER-BASED POLYMER AND EXPANDED POLYMER PARTICLES|FR1363253A| FR3015251B1|2013-12-20|2013-12-20|COSMETIC COMPOSITION COMPRISING A CARBOSILOXANE DENDRIMER-BASED POLYMER AND EXPANDED POLYMER PARTICLES|

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EP14830632.7A| EP3082958A2|2013-12-20|2014-12-11|Cosmetic composition comprising a polymer bearing a carbosiloxane dendrimer unit and expanded polymer particles|

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BR112016014459A| BR112016014459A2|2013-12-20|2014-12-11|cosmetic composition and its non-therapeutic use and process for makeup and / or care of keratinous materials, particularly the skin|

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RU2016128906A| RU2016128906A|2013-12-20|2014-12-11|A COSMETIC COMPOSITION CONTAINING A POLYMER CARRYING A LINK OF A CARBOSILOXANE DANDRIMER AND FOAMED POLYMER PARTICLES|

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US15/106,341| US20160331672A1|2013-12-20|2014-12-11|Cosmetic composition comprising a polymer bearing a carbosiloxane dendrimer unit and expanded polymer particles|

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CN201480076143.9A| CN106170280A|2013-12-20|2014-12-11|Including with the cosmetic composition of the polymer of carbon siloxanes dendritic macromole unit and expanded polymer particles|

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KR1020167019479A| KR20160096197A|2013-12-20|2014-12-11|Cosmetic composition comprising a polymer bearing a carbosiloxane dendrimer unit and expanded polymer particles|

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PCT/IB2014/066809| WO2015092632A2|2013-12-20|2014-12-11|Cosmetic composition comprising a polymer bearing a carbosiloxane dendrimer unit and expanded polymer particles|

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JP2016541172A| JP2017502953A|2013-12-20|2014-12-11|Cosmetic composition comprising a polymer having carbosiloxane dendrimer units and expanded polymer particles|